Pickett's charge [[electronic resource] ] : the last attack at Gettysburg / / Earl J. Hess

• Record Nr.: UNINA9910463799403321
• Autore: Hess Earl J
• Pubbl/distr/stampa: Chapel Hill, : University of North Carolina Press, c2001
• ISBN: 0-8078-9839-2; 1-4696-0300-4
• Descrizione fisica: 1 online resource (518 p.)
• Collana: Civil War America
• Disciplina: 973.7/349
• Soggetti: Gettysburg, Battle of, Gettysburg, Pa., 1863; Electronic books.
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references (p. 459-482) and index.
• Nota di contenuto: Machine generated contents note: Preface, xiii -- Chapter 1. The Last Attack at Gettysburg, 1 -- Chapter 2. The Attackers, 36 -- Chapter 3. The Defenders, 82 -- Chapter 4. The Bombardment, 125 -- Chapter 5. To Emmitsburg Road, 166 -- Chapter 6. To the Stone Fence, 201 --Chapter 7. High Tide, 248 -- Chapter 8. The Repulse, 296 -- Chapter 9. Glory Enough, 341 -- Epilogue: Making Sense of Pickett's Charge, 385 -- Order of Battle, 405 --Notes, 409 -- Bibliography, 459 --Index,483.
• Sommario/riassunto: Pickett's Charge is probably the best-known military engagement of the Civil War, widely regarded as the defining moment of the battle of Gettysburg and celebrated as the high-water mark of the Confederacy. But as this book notes, the epic stature of Pickett's Charge has grown at the expense of reality, and the facts of the attack have been obscured or distorted by the legend that surrounds them. The book aims to sweep away the accumulated myths about Pickett's Charge.

The chemistry of 1,2,3-Thiadiazoles [[electronic resource] /] / Vasiliy A. Bakulev, Wim Dehaen

• Record Nr.: UNINA9910831037703321
• Autore: Bakulev Vasiliy A
• Pubbl/distr/stampa: Hoboken, N.J., : John Wiley & Sons, c2004
• ISBN: 1-280-54200-4; 9786610542000; 0-471-65699-2; 0-471-65691-7
• Descrizione fisica: 1 online resource (261 p.)
• Collana: The chemistry of heterocyclic compounds ; ; v. 62
• Altri autori (Persone): DehaenW (Wim)
• Disciplina: 547.59; 547.594; 547/.59/05
• Soggetti: Thiadiazoles
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: THE CHEMISTRY OF 1,2,3-THIADIAZOLES; The Chemistry of Heterocyclic Compounds Introduction to the Series; Preface; Acknowledgments; Contents; 1 Synthesis of 1,2,3-thiadiazoles; 1.1 Cyclization of Hydrazones with Thionyl Chloride (Hurd-Mori Synthesis); 1.1.1 Scope and Limitations; 1.1.2 Mechanism of the Hurd-Mori Reaction; 1.1.3 Application of the Hurd-Mori Reaction in Organic Synthesis; 1.2 Cycloaddition of Diazoalkanes onto a C=S bond (Pechmann Synthesis); 1.3 Heterocyclization of α-diazo Thiocarbonyl Compounds (Wolff Synthesis); 1.3.1 Introduction of a Diazo Function into Compounds Containing a C=S Bond1.3.2 Introduction of a C=S Bond in the α-position to a Diazo Group; 1.3.3 Simultaneous Introduction of Diazo and Thiocarbonyl Functions; 1.4 Transformations of other Sulfur-containing Heterocyclic Compounds; 1.5 Elaboration of Preformed 1,2,3-Thiadiazoles; 1.5.1 Carboxylic Acids; 1.5.2 Functional Derivatives of Carboxylic Acids; 1.5.3 Aldehydes; 1.5.4 Amino-1,2,3-Thiadiazoles; 1.5.5 Halo Derivatives; 1.5.6 5-Hydrazino-, 5-Mercapto-1,2,3-Thiadiazoles and 5-Sulfide Derivatives; 1.5.7 2-(1,2,3-Thiadiazol-5-yl)acetic Acid Derivatives1.5.8 Alkenyl-1,2,3-Thiadiazoles; 1.5.9 5-Hydroxyiminomethyl- and 5-Diazomethyl-1,2,3-Thiadiazoles; 1.5.10 4-Hydroxymethyl-1,2,3-Thiadiazoles; 1.6 Tables; 1.7 Selected Procedures; 1.7.1 1,2,3-Thiadiazole-4-Carbaldehyde; 1.7.2 4-Phenyl-1,2,3-Thiadiazole; 1.7.3 4-Phenyl-1,2,3-Thiadiazole-5-Carbaldehyde; 1.7.4 4-Phenyl-5-Oxyiminomethyl-1,2,3-Thiadiazole; 1.7.5 5-Phenyl-1,2,3-Thiadiazole-4-Carbaldehyde; 1.7.6 5-Chloro-1,2,3-Thiadiazole-4-Carbaldehyde; 1.7.7 Ethyl 5-amino-1,2,3-Thiadiazole-4-Carboxylate; 1.7.7.1 Pechmann Method; 1.7.7.2 Wolff Method1.7.8 Ethyl 5-chloro-1,2,3-Thiadiazole-4-Carboxylate; 1.7.9 4-Phenyl-2-(2,4,6-Trichlorophenyl)-1,2,3-Thiadiazolium Chloride; 1.7.10 5-Amino-4-ethoxycarbonyl-2-phenyl-1,2,3-thiadiazolium bromide; References; 2 Structure of 1,2,3-Thiadiazoles; 2.1 Theoretical Methods; 2.2 Experimental Structural Methods; 2.2.1 X-ray Analysis; 2.2.2 Nuclear Magnetic Resonance Spectroscopy; 2.2.2.1 Proton NMR Spectroscopy; 2.2.2.2 Carbon-13 NMR Spectroscopy; 2.2.2.3 Nitrogen-14 NMR Spectroscopy; 2.2.2.4 Nitrogen-15 NMR Spectroscopy; 2.2.3 Mass Spectrometry; 2.2.4 Other Spectroscopic Data; References3 Chemical Properties of 1,2,3-Thiadiazoles; 3.1 Reactions due to the Reactivity of Ring Atoms; 3.1.1 Reactions with Electrophiles; 3.1.1.1 Protonation; 3.1.1.2 Complexation; 3.1.1.3 Alkylation; 3.1.1.4 Acylation; 3.1.1.5 Oxidation; 3.1.1.6 Electrophilic Substitution of Hydrogen; 3.1.2 Reactions with Nucleophiles; 3.1.2.1 Attack at the Sulfur Atom; 3.1.2.2 Attack at the C(5) Atom; 3.1.2.3 Attacks at H(4) and H(5); 3.1.2.4 Cycloaddition Reactions; 3.2 Reactions of Substituents; 3.2.1 5-Alkyl-1,2,3-thiadiazoles; 3.2.2 1,2,3-Thiadiazole-4-carbaldehyde; 3.2.3 5-Amino-1,2,3-thiadiazole-4-carbothioamide
• Sommario/riassunto: 1,2,3-Thiadiazoles are a group of heterocycles whose derivatives are important in industry, medicine, and agriculture. This volume provides a complete treatment of this group of heterocycles with an emphasis on syntheses, structural data, properties, reactions, and applications.