|
|
|
|
|
|
|
|
1. |
Record Nr. |
UNINA9910454980603321 |
|
|
Autore |
Williams Andrew <1937-> |
|
|
Titolo |
Free energy relationships in organic and bio-organic chemistry [[electronic resource] /] / Andrew Williams |
|
|
|
|
|
|
|
Pubbl/distr/stampa |
|
|
Cambridge, U.K., : RSC, c2003 |
|
|
|
|
|
|
|
ISBN |
|
|
|
|
|
|
Descrizione fisica |
|
1 online resource (313 p.) |
|
|
|
|
|
|
Disciplina |
|
|
|
|
|
|
Soggetti |
|
Linear free energy relationship |
Electronic books. |
|
|
|
|
|
|
|
|
Lingua di pubblicazione |
|
|
|
|
|
|
Formato |
Materiale a stampa |
|
|
|
|
|
Livello bibliografico |
Monografia |
|
|
|
|
|
Note generali |
|
Description based upon print version of record. |
|
|
|
|
|
|
Nota di bibliografia |
|
Includes bibliographical references and index. |
|
|
|
|
|
|
Nota di contenuto |
|
01PRELIM; 02PREFA; 03CONT; 04CHAP01; 05CHAP02; 06CHAP03; 07CHAP04; 08CHAP05; 09CHAP06; 10CHAP07; 11APPEN1; 12APPEN2; 13APPEN3; 14APPEN4; 15INDEX |
|
|
|
|
|
|
|
|
Sommario/riassunto |
|
Introducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for th |
|
|
|
|
|
|
|