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1. |
Record Nr. |
UNINA9910141261103321 |
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Autore |
Kamer Paul |
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Titolo |
Phosphorus(III) ligands in homogeneous catalysis [[electronic resource] ] : design and synthesis / / edited by Paul Kamer & Piet W.N.M. van Leeuwen |
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Pubbl/distr/stampa |
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Chichester, West Sussex, United Kingdom, : John Wiley & Sons, Ltd., 2012 |
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ISBN |
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1-280-78471-7 |
9786613695109 |
1-118-29970-1 |
1-118-29971-X |
1-118-29973-6 |
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Descrizione fisica |
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1 online resource (567 p.) |
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Classificazione |
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Altri autori (Persone) |
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LeeuwenP. W. N. M. van (Piet W. N. M.) |
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Disciplina |
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541.2242 |
546.712595 |
546/.712595 |
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Soggetti |
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Phosphorus compounds |
Ligands |
Catalysis |
TECHNOLOGY & ENGINEERING / Material Science |
Electronic books. |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Phosphorus( III ) Ligands in Homogeneous Catalysis: Design and Synthesis; Contents; List of Contributors; Preface; 1 Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design; 1.1 Introduction; 1.2 Properties of phosphorus ligands; 1.2.1 Electronic ligand parameters; 1.2.2 Steric ligand parameters; 1.2.3 Bite angle effects; 1.2.4 Molecular electrostatic potential (MESP) approach; 1.3 Asymmetric ligands; 1.4 Rational ligand design in nickel-catalysed hydrocyanation; 1.4.1 Introduction; 1.4.2 Mechanistic insights; 1.4.3 Rational design; 1.5 Conclusions; References |
2 Chiral Phosphines and Diphosphines2.1 Introduction; 2.1.1 Early developments; 2.2 Chiral chelating diphosphines with a linking |
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scaffold; 2.2.1 Building chiral backbones from naturally available materials; 2.2.2 Design and synthesis of chiral backbones; 2.2.3 Synthesis from optical resolution of phosphine precursors or intermediates; 2.3 Chiral atropisomeric biaryl diphosphines; 2.3.1 Synthesis of BINAP and its derivatives; 2.3.2 Synthesis of atropisomeric biaryl ligands; 2.3.3 General strategies of synthesizing of atropisomeric biaryl ligands; 2.4 Chiral phosphacyclic diphosphines |
2.4.1 Fundamental discovery and syntheses of BPE and DuPhos2.4.2 Design and synthesis of bisphosphetanes; 2.4.3 Design and synthesis of bisphospholanes; 2.4.4 Design and synthesis of bisphospholes; 2.4.5 Design and synthesis of bisphosphinanes; 2.4.6 Design and synthesis of bisphosphepines; 2.4.7 Summary of synthetic strategies of phosphacycles; 2.5 P-stereogenic diphosphine ligands; 2.6 Experimental procedures for the syntheses of selected diphosphine ligands; 2.6.1 Synthesis procedure for DIOP* ligand; 2.6.2 Synthesis procedure of SDP ligands; 2.6.3 Synthesis procedure of (R,R)-BICP |
2.6.4 Synthesis procedure of SEGPHOS2.6.5 Synthesis procedure of Ph-BPE; 2.6.6 Synthesis procedure of TangPhos; 2.6.7 Synthesis procedure of Binaphane; 2.7 Concluding remarks; References; 3 Design and Synthesis of Phosphite Ligands for Homogeneous Catalysis; 3.1 Introduction; 3.2 Synthesis of phosphites; 3.2.1 Monophosphites; 3.2.2 Diphosphite ligands; 3.2.3 Triphosphites; 3.3 Highlights of catalytic applications of phosphite ligands; 3.3.1 Hydrogenation reactions; 3.3.2 Functionalization of alkenes: hydroformylation and hydrocyanation |
3.3.3 Addition of nucleophiles to carbonyl compounds and derivatives3.3.4 Allylic substitution reactions; 3.3.5 Miscellaneous reactions; 3.4 General synthetic procedures; 3.4.1 Symmetrically substituted phosphites; 3.4.2 Nonsymmetrically substituted phosphites; 3.4.3 Phosphites bearing dioxaphospho-cyclic units; References; 4 Phosphoramidite Ligands; 4.1 Introduction; 4.1.1 History; 4.2 Synthesis of phosphoramidites; 4.3 Reactivity of the phosphoramidites; 4.4 Types of phosphoramidite ligands; 4.4.1 Acyclic monodentate phosphoramidites; 4.4.2 Cyclic monodentate phosphoramidites based on diols |
4.4.3 Cyclic phosphoramidites based on amino alcohols |
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Sommario/riassunto |
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"Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the acknowledged catalytic reactions. The positive effects of phosphine ligands in transition metal homogeneous catalysis have contributed largely to the evolution of the field into an indispensable tool in organic synthesis and the industrial production of chemicals.This book aims to address the design and synthesis of a comprehensive compilation of P(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their challenging synthesis.Topics covered include ligand effects in homogeneous catalysis and rational catalyst design, P-stereogenic ligands, calixarenes, supramolecular approaches, solid phase synthesis, biological approaches, and solubility and separation.Ligand families covered in this book include phosphine, diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite, phosphinite, phosphole, phosphinine, phosphinidenene, phosphaalkenes, phosphaalkynes, P-chiral ligands, and cage ligands.Each ligand class is accompanied by detailed and reliable synthetic procedures. Often the rate limiting step in the application of ligands in catalysis is the synthesis of the ligands |
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themselves, which can often be very challenging and time consuming. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice.Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic chemistry"-- |
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2. |
Record Nr. |
UNINA9910451153303321 |
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Autore |
Matthew Neil |
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Titolo |
Beginning Linux Programming [[electronic resource]] |
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Pubbl/distr/stampa |
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Chichester, : Wiley, 2008 |
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ISBN |
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1-118-05861-5 |
1-281-10043-9 |
9786611100438 |
0-470-24913-7 |
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Edizione |
[4th ed.] |
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Descrizione fisica |
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1 online resource (818 p.) |
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Collana |
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Wrox programmer to programmer |
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Altri autori (Persone) |
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Disciplina |
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Soggetti |
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Linux |
Operating systems (Computers) |
Engineering & Applied Sciences |
Computer Science |
Electronic books. |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di contenuto |
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Beginning Linux Programming, 4th Edition; About the Authors; Credits; Acknowledgments; Contents; Foreword; Introduction; Who's This Book For?; What's Covered in the Book; What You Need to Use This Book; Source Code; Conventions; Errata; p2p.wrox.com; Chapter 1: Getting Started; An Introduction to UNIX, Linux, and GNU; Programming Linux; Getting Help; Summary; Chapter 2: Shell Programming; Why Program with a Shell?; A Bit of Philosophy; What Is a Shell?; Pipes and |
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Redirection; The Shell as a Programming Language; Shell Syntax; Going Graphical - The dialog Utility; Putting It All Together |
SummaryChapter 3: Working with Files; Linux File Structure; System Calls and Device Drivers; Library Functions; Low-Level File Access; The Standard I/O Library; Formatted Input and Output; File and Directory Maintenance; Scanning Directories; Errors; The /proc File System; Advanced Topics: fcntl and mmap; Summary; Chapter 4: The Linux Environment; Program Arguments; Environment Variables; Time and Date; Temporary Files; User Information; Host Information; Logging; Resources and Limits; Summary; Chapter 5: Terminals; Reading from and Writing to the Terminal; Talking to the Terminal |
The Terminal Driver and the General Terminal InterfaceThe termios Structure; Terminal Output; Detecting Keystrokes; Summary; Chapter 6: Managing Text-Based Screens with curses; Compiling with curses; Curses Terminology and Concepts; The Screen; The Keyboard; Windows; Subwindows; The Keypad; Using Color; Pads; The CD Collection Application; Summary; Chapter 7: Data Management; Managing Memory; File Locking; Databases; The CD Application; Summary; Chapter 8: MySQL; Installation; MySQL Administration; Accessing MySQL Data from C; The CD Database Application; Summary; Chapter 9: Development Tools |
Problems of Multiple Source FilesThe make Command and Makefiles; Source Code Control; Writing a Manual Page; Distributing Software; RPM Packages; Other Package Formats; Development Environments; Summary; Chapter 10: Debugging; Types of Errors; General Debugging Techniques; Debugging with gdb; More Debugging Tools; Assertions; Memory Debugging; Summary; Chapter 11: Processes and Signals; What Is a Process?; Process Structure; Starting New Processes; Signals; Summary; Chapter 12: POSIX Threads; What Is a Thread?; Advantages and Drawbacks of Threads; A First Threads Program |
Simultaneous ExecutionSynchronization; Thread Attributes; Canceling a Thread; Threads in Abundance; Summary; Chapter 13: Inter-Process Communication: Pipes; What Is a Pipe?; Process Pipes; Sending Output to popen; The Pipe Call; Parent and Child Processes; Named Pipes: FIFOs; The CD Database Application; Summary; Chapter 14: Semaphores, Shared Memory, and Message Queues; Semaphores; Shared Memory; Message Queues; The CD Database Application; IPC Status Commands; Summary; Chapter 15: Sockets; What Is a Socket?; Socket Connections; Network Information; Multiple Clients; Datagrams; Summary |
Chapter 16: Programming GNOME Using GTK+ |
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Sommario/riassunto |
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Beginning Linux Programming, Fourth Edition continues its unique approach to teaching UNIX programming in a simple and structured way on the Linux platform. Through the use of detailed and realistic examples, students learn by doing, and are able to move from being a Linux beginner to creating custom applications in Linux. The book introduces fundamental concepts beginning with the basics of writing Unix programs in C, and including material on basic system calls, file I/O, interprocess communication (for getting programs to work together), and shell programming. Parallel to this, the b |
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