1.

Record Nr.

UNINA9910451137603321

Autore

Baer Tomas

Titolo

Unimolecular reaction dynamics [[electronic resource] ] : theory and experiments / / Tomas Baer and William L. Hase

Pubbl/distr/stampa

New York, : Oxford University Press, 1996

ISBN

0-19-756029-6

1-280-52620-3

9786610526208

0-19-536059-1

1-4294-1537-1

Descrizione fisica

1 online resource (447 p.)

Collana

The international series of monographs on chemistry ; ; 31

Altri autori (Persone)

HaseWilliam L

Disciplina

541.3/93

Soggetti

Unimolecular reactions

Chemistry

Electronic books.

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Previously issued in print: 1996.

Nota di bibliografia

Includes bibliographical references and indexes.

Nota di contenuto

Contents; 1. Introduction; 2. Vibrational/Rotational Energy Levels; 3. Potential Energy Surfaces; 4. State Preparation and Intramolecular Vibrational Energy Redistribution; 5. Experimental Methods in Unimolecular Dissociation Studies; 6. Theory of Unimolecular Decomposition-The Statistical Approach; 7. Applications and Extensions of Statistical Theories; 8. Dynamical Approaches to Unimolecular Rates; 9. Product Energy Distributions; 10. The Dissociation of Small and Large Clusters; Appendix; Author Index; Subject Index

Sommario/riassunto

The book provides a penetrating and comprehensive description of energy selected reactions from a theoretical as well as experimental point of view. It presents three major aspects of unimolecular reactions involving the preparation of the reactants in selected energy states, the rate of dissipation of the activated molecule, and the partitioning of the excess energy among the final products.