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Record Nr. |
UNINA9910392720803321 |
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Autore |
Hellwig Raphael |
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Titolo |
Alkyne‐Based Nanostructures on Silver Substrates [[electronic resource] /] / by Raphael Hellwig |
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Pubbl/distr/stampa |
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Cham : , : Springer International Publishing : , : Imprint : Springer, , 2018 |
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ISBN |
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Edizione |
[1st ed. 2018.] |
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Descrizione fisica |
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1 online resource (132 pages) |
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Collana |
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Springer Theses, Recognizing Outstanding Ph.D. Research, , 2190-5053 |
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Disciplina |
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Soggetti |
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Nanoscale science |
Nanoscience |
Nanostructures |
Organometallic chemistry |
Materials—Surfaces |
Thin films |
Nanoscale Science and Technology |
Organometallic Chemistry |
Surfaces and Interfaces, Thin Films |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Nota di contenuto |
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Introduction -- Experimental Methods -- Silver-bis-acetylide Wires -- Fabrication of Graphdiyne Nanowires -- Metal Alkynyl 22/7 Complexes -- Ho-Catalyzed Cyclotrimerization -- Conclusion and Outlook. |
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Sommario/riassunto |
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Acetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the author establishes protocols to fabricate regular architectures built up by the on-surface |
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