Highly Luminescent Lanthanide Complexes with Specific Coordination Structures [[electronic resource] /] / by Kohei Miyata

• Record Nr.: UNINA9910298647003321
• Autore: Miyata Kohei
• Pubbl/distr/stampa: Tokyo : , : Springer Japan : , : Imprint : Springer, , 2014
• ISBN: 4-431-54944-7
• Edizione: [1st ed. 2014.]
• Descrizione fisica: 1 online resource (100 p.)
• Collana: Springer Theses, Recognizing Outstanding Ph.D. Research, , 2190-5053
• Disciplina: 546.4
• Soggetti: Inorganic chemistry; Optical materials; Electronic materials; Physical chemistry; Inorganic Chemistry; Optical and Electronic Materials; Physical Chemistry
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references.
• Nota di contenuto: General Introduction -- Luminescence Properties of Thermostable Lanthanide Coordination Polymers with Intermolecular Interactions -- Chameleon Luminophore for a Wide Range Temperature-Sensor Composed of Lanthanide Coordination Polymers -- Characteristic Structures and Photophysical Properties of Nona-coordinated Eu(III) Complexes with Tridentate Phosphine Oxides -- Photophysical Properties of Lanthanide Complexes with Asymmetric Dodecahedron Structures -- Solvent-dependent Luminescence of Octa-coordinated Eu(III) Complexes -- Summary.
• Sommario/riassunto: This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational ; frequency C–H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C–F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.