Halogen Bonding II : Impact on Materials Chemistry and Life Sciences / / edited by Pierangelo Metrangolo, Giuseppe Resnati

• Record Nr.: UNINA9910298608903321
• Pubbl/distr/stampa: Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015
• ISBN: 3-319-15732-9
• Edizione: [1st ed. 2015.]
• Descrizione fisica: 1 online resource (IX, 208 p. 130 illus., 66 illus. in color.)
• Collana: Topics in Current Chemistry, , 0340-1022 ; ; 359
• Disciplina: 546.73
• Soggetti: Inorganic chemistry; Organic chemistry; Medicinal chemistry; Inorganic Chemistry; Organic Chemistry; Medicinal Chemistry
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Bibliographic Level Mode of Issuance: Monograph
• Nota di contenuto: Intro -- Preface -- References -- Contents -- Characteristics of a sigma-Hole and the Nature of a Halogen Bond -- 1 Introduction -- 2 Methods -- 2.1 Isolated Subsystems -- 2.2 SAPT Decomposition -- 2.3 Complexes -- 3 Results and Discussion -- 3.1 Halogenated Molecules -- 3.2 Complexes -- 4 Conclusions -- References -- Anion Recognition in Solution via Halogen Bonding -- 1 Introduction -- 2 Interactions of Anions with Monodentate Halogen Bond Donors -- 2.1 Molecular Halogen or Interhalogen Donors -- 2.2 Monodentate Haloorganic Donors -- 3 Multidentate Halogen Bond Donors as Anion Receptors -- 4 Anion Recognition with Cationic Halogen Bond Donors -- 5 Anion Recognition Through Combinations of Halogen and Hydrogen Bonding -- 6 Summary, Conclusions, and Outlook -- References -- Halogen Bonding in Solution -- 1 Introduction -- 2 Neutral, Two-Center Halogen Bond Complexes -- 3 Charged, Two-Center Halogen Bond Complexes -- 4 Neutral, Three-Center Halogen Bond Complexes -- 5 Charged, Three-Center Halogen Bond Complexes -- 6 Conclusions and Outlook -- 7 Addendum -- References -- ; Halonium Ions as Halogen Bond Donors in the Solid State [XL2]Y Complexes -- 1 Introduction -- 1.1 Halogen Bond: The Long Lost Brother of the Hydrogen Bond -- 1.2 . or Simply a Charge Transfer Interaction? -- 2 Halonium-Nitrogen Complexes -- 2.1 Aromatic sp2 Nitrogen -- 2.2 Halonium to sp and Other sp2 Nitrogens -- 2.3 Halonium to sp3 Nitrogens -- 3 Halonium-Sulfur Complexes -- 4 Halonium-Selenium and Halonium-Tellurium Complexes -- References -- Organizing Radical Species in the Solid State with Halogen Bonding -- 1 Introduction -- 2 Radicals as Halogen Bond Donors -- 2.1 Halogenated Trioxytriangulene Radical -- 2.2 TTF Radical Cations Salts: Toward Chiral Conductors -- 2.2.1 IodoTTFs with Non-centrosymmetric ClO4- Anion -- 2.2.2 IodoTTFs with Halogen Bonding to Chiral Anions.; 2.2.3 Chiral IodoTTF Salts -- 2.3 Paramagnetic Metal Complexes with Halogenated Ligands -- 2.3.1 Halopyridine Complexes of Metal Halides -- 2.3.2 Spin Crossover Cooperativity and Halogen Bonding -- 3 Radicals as Halogen Bond Acceptors -- 3.1 Nitronyl Radicals -- 3.2 Metal Complexes with Essentially Metallic Spin Density -- 3.3 Metal Complexes with Non-innocent Ligands -- 4 Halogen-Bonded Charge Transfer Salts -- 5 Summary, Conclusions, and Outlook -- References -- Halogen Bonding in the Design of Organic Phosphors -- 1 Introduction -- 2 New Strategy of Introducing Metal-Free Heavy Atom Perturber by Halogen Bonding in Defined Stoichiometry -- 2.1 Halogen Bonding Acceptors as Phosphors -- 2.2 Donors as Heavy Atom Perturbing Sources -- 2.3 Advantages of Halogen Bonding -- 3 Phosphorescent Cocrystals Assembled by the New Strategy -- 3.1 Structural Features of Cocrystals -- 3.1.1 Cocrystals by PAHs and Haloperfluorobenzenes -- 3.1.2 Cocrystals by Fluorene and Its Heterocyclic Analogues and Haloperfluorobenzenes -- 3.2 Phosphorescent Properties of Cocrystals -- 3.2.1 Emission from PAHs in Cocrystals -- 3.2.2 Emission from Fluorene or Its Heterocyclic Analogues in Cocrystals -- 4 Concluding Remarks -- References -- Halogen-Bonded Photoresponsive Materials -- 1 Preface -- 2 Introduction to Azobenzene -- 3 Photoinduced Surface Patterning in Azopolymers: What Does Halogen Bonding Have to Offer? -- 4 Photoactive Halogen-Bonded Liquid Crystals -- 5 Halogen-Bonded Crystals That Move -- 6 Conclusions -- References -- Halogen Bonds in Organic Synthesis and Organocatalysis -- 1 Hydrogen Bonding in Non-covalent Organocatalysis -- 2 Halogen Bonding in Organic Synthesis and Non-covalent Organocatalysis -- 2.1 Further Directional Interaction: Halogen Bonding -- 2.2 Overview and Scope -- 2.3 Solely-Halogen-Based Halogen-Bond Donors -- 2.3.1 Elemental Halogens.; 2.3.2 Interhalogen Compounds -- 2.4 N-X-Based Halogen-Bond Donors -- 2.5 C-X-Based Halogen-Bond Donors -- 2.5.1 Monodentate Halogen-Bond Donors -- 2.5.2 Multidentate Halogen-Bond Donors -- Proof-of-Principle Reaction -- Isothermal Calorimetric Titrations -- Halopyridinium-Based Halogen-Bond Donors as Activators -- Triazolium-Based Halogen-Bond Donors as Activators -- Polyfluorinated Azo-Bridged Halogen-Bond Donors -- Polyfluorinated Halogen-Bond Donors as Organocatalysts -- 3 Summary and Outlook -- References -- Index.
• Sommario/riassunto: The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger ; scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.