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Record Nr. |
UNINA9910254042503321 |
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Autore |
Jiang Huanfeng |
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Titolo |
Haloalkyne Chemistry / / by Huanfeng Jiang, Chuanle Zhu, Wanqing Wu |
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Pubbl/distr/stampa |
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Berlin, Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2016 |
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ISBN |
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Edizione |
[1st ed. 2016.] |
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Descrizione fisica |
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1 online resource (86 p.) |
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Collana |
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SpringerBriefs in Green Chemistry for Sustainability, , 2212-9898 |
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Disciplina |
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Soggetti |
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Organic chemistry |
Optical materials |
Electronic materials |
Medicinal chemistry |
Organic Chemistry |
Optical and Electronic Materials |
Medicinal Chemistry |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references at the end of each chapters. |
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Nota di contenuto |
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Preface; Contents; Abbreviations; 1 Introduction; Abstract; References; 2 Preparation of Haloalkynes; Abstract; References; 3 Reactions of Haloalkynes; Abstract; 3.1 Transformations of Carbon-Halo Bond Motif; 3.1.1 Construction of Carbon-Carbon Bond; 3.1.1.1 Construction of C(sp)--C(sp) Bond; C(sp)--C(sp) Homo-Coupling; C(sp)--C(sp) Cross-Coupling; 3.1.1.2 Construction of C(sp)--C(sp2) Bond; C(sp)--C(sp2) Cross-Coupling; Alkynylation Reactions; 3.1.1.3 Construction of C(sp)--C(sp3) Bond; 3.1.2 Construction of Carbon-Nitrogen Bond; 3.1.3 Construction of Carbon-Sulfur Bond |
3.1.4 Construction of Carbon-Phosphorus Bond3.2 Transformations of Carbon-Carbon Triple Bond Motif; 3.2.1 Nucleophilic Additions; 3.2.1.1 Halogen Nucleophiles; 3.2.1.2 Boron Nucleophiles; 3.2.1.3 Carbon Nucleophiles; 3.2.1.4 Nitrogen Nucleophiles; 3.2.1.5 Oxygen Nucleophiles; 3.2.1.6 Sulfur Nucleophiles; 3.2.2 Cycloadditions; 3.2.2.1 [2 + 2] Cycloaddition; 3.2.2.2 [3 + 2] Cycloaddition; 3.2.2.3 [4 + 2] and [2 + 2 + 2] Cycloadditions; 3.3 Transformations Involved Both Carbon-Halo Bond and Carbon-Carbon Triple Bond Motif; 3.3.1 Initially Reacted |
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at the Carbon-Halo Bond |
3.3.2 Initially Reacted at the Carbon-Carbon Triple BondReferences; 4 Conclusions and Outlook; Abstract |
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Sommario/riassunto |
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This book presents efficient and practical methods for the synthesis of various functionalized organic molecules from haloalkynes through different reaction processes such as cross-coupling reactions, nucleophilic additions and cycloadditions. It consists of four chapters demonstrating interesting examples of these transformations, and showcasing the synthetic power of haloalkynes for rapid assembly of complex molecular structures. Most of the protocols allow multiple bond-forming events to occur in a single operation, offering opportunities to advance chemical synthesis and address the increasing demands for green and sustainable chemistry. It also presents a wide range of functionalized products, including many synthetically useful conjugated cyclic and acyclic structures that have potential applications in materials science, chemical biology and natural product synthesis. This book is a valuable reference not only for organic chemists, but also for biologists and materials scientists involved in the modern synthesis of organic compounds and materials. Huanfeng Jiang and Wanqing Wu are both Professors at the School of Chemistry and Chemical Engineering, South China University of Technology, China. Chuanle Zhu is a Postdoctoral Fellow at the School of Chemistry and Chemical Engineering, South China University of Technology, China. |
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