Aqueous-phase organometallic catalysis [[electronic resource] ] : concepts and applications / / edited by Boy Cornils and Wolfgang A. Herrmann

• Record Nr.: UNINA9910146237003321
• Pubbl/distr/stampa: Weinheim, : Wiley-VCH, c2004
• ISBN: 1-280-52055-8; 9786610520558; 3-527-60546-0; 3-527-60248-8
• Edizione: [2nd, completely rev. and enl. ed.]
• Descrizione fisica: 1 online resource (782 p.)
• Collana: Green chemistry
• Altri autori (Persone): CornilsBoy; HerrmannW. A (Wolfgang A.)
• Disciplina: 660.2995; 660/.2995
• Soggetti: Catalysis; Metal catalysts; Water-soluble organometallic compounds; Catalysts - Recycling; Heterogeneous catalysis; Electronic books.
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Aqueous-Phase Organometallic Catalysis; Preface to the Second Edition; Preface to the First Edition; Contents; Contributors; 1 Introduction; 1 Introduction; 2 Basic Aqueous Chemistry; 2.1 Organic Chemistry in Water; 2.1.1 Introduction; 2.1.2 Origin of the Reactivity in Water; 2.1.3 Pericyclic Reactions; 2.1.3.1 Diels - Alder Reactions; 2.1.3.2 Hetero Diels - Alder Reactions; 2.1.3.3 Other Cycloadditions; 2.1.3.4 Claisen Rearrangements; 2.1.4 Carbonyl Additions; 2.1.4.1 Aldol-type Reactions; 2.1.4.2 Michael-type Reactions; 2.1.4.3 Allylation Reactions; 2.1.5 Oxido-reductions; 2.1.5.1 Oxidations2.1.5.2 Reductions; 2.1.6 Radical Reactions; 2.1.7 Outlook; 2.2 Organometallic Chemistry in Water; 2.2.1 Introduction; ; 2.2.2 Water as a Solvent and Ligand; 2.2.3 Organometallic Reactions of Water; 2.2.4 Catalytic Reactions with Water; 2.2.4.1 Water-gas Shift Reaction; 2.2.4.2 Wacker- Hoechst Acetaldehyde Process; 2.2.4.3 Olefin Hydration; 2.2.4.4 Hydrodimerization; 2.2.5 Water-soluble Metal Complexes; 2.2.6 Perspectives; 2.3 Characterization of Organometallic Compounds in Water; 2.3.1 Introduction; 2.3.2 General Survey; 2.3.3 Effect of High Hydrostatic Pressure on Aqueous Organometallic Systems2.3.4 Aqueous Organometallics with Pressurized Gases; 2.3.5 Concluding Remarks; 3 Catalysts for an Aqueous Catalysis; 3.1 Variation of Central Atoms; 3.1.1 Transition Metals; 3.1.1.1 Introduction; 3.1.1.2 Water-soluble Catalysts by Virtue of Water-soluble Ligands; 3.1.1.3 Water-soluble Catalysts through Water Coordination; 3.1.2 Lanthanides in Aqueous-phase Catalysis; 3.1.2.1 Introduction; 3.1.2.2 Aldol Reactions; 3.1.2.3 Mannich-type Reactions; 3.1.2.4 Diels - Alder Reactions; 3.1.2.5 Micellar Systems; 3.1.2.6 Asymmetric Catalysis in Aqueous Media3.1.2.7 Conclusions; 3.2 Variation of Ligands; 3.2.1 Monophosphines; 3.2.1.1 General Features, Scope, and Limitations; 3.2.1.2 Anionic Phosphines; 3.2.1.3 Cationic Phosphines; 3.2.1.4 Nonionic Water-soluble Phosphines; 3.2.2 Diphosphines and Other Phosphines; 3.2.2.1 General; 3.2.2.2 Diphosphines - Introduction of Sulfonate Groups by Direct Sulfonation; 3.2.2.3 Introduction of Sulfonate Groups During Synthesis; 3.2.2.4 Diphosphines with Quaternized Aminoalkyl or Aminoaryl Groups; 3.2.2.5 Diphosphines with Hydroxyalkyl or Polyether Substituents; 3.2.2.6 Carboxylated Diphosphines3.2.2.7 Amphiphilic Diphosphines; 3.2.2.8 Other Phosphines; 3.2.3 Ligands or Complexes Containing Ancillary Functionalities; 3.2.3.1 Complexes Containing at Least Two Classical Functionalities; 3.2.3.2 Cationic Complexes; 3.2.3.3 Immobilization on Silica Supports; 3.2.3.4 Macromolecular Ligands or Supports; 3.2.3.5 Ligands not Containing Phosphorus; 3.2.3.6 Additional Perspectives; 3.2.4 Tenside Ligands; 3.2.4.1 Introduction; 3.2.4.2 Tenside Phosphines and Amines; 3.2.4.3 Hydroformylation Reactions Catalyzed by Transition Metal Surfactant - Phosphine Complexes; 3.2.4.4 Hydrogenation Reactions Catalyzed by Transition Metal Surfactant - Phosphine Complexes
• Sommario/riassunto: Now in its second completely revised and expanded edition. Written by the renowned editors B. Cornils and W. A. Herrmann, this book presents every important aspect of aqueous-phase organometallic catalysis, a method which saves time, waste and money. The large-scale application of this ""green"" technology in chemical industry clearly underlines its practical use outside of academia.New chapters (for example ""Organic Chemistry in Water""), 20% more content and fully updated contributions from by a plethora of international authors make this book a ""must-have"" for everyone working in thi

Unimolecular reaction dynamics [[electronic resource] ] : theory and experiments / / Tomas Baer and William L. Hase

• Record Nr.: UNINA9910777040503321
• Autore: Baer Tomas
• Pubbl/distr/stampa: New York, : Oxford University Press, 1996
• ISBN: 0-19-756029-6; 1-280-52620-3; 9786610526208; 0-19-536059-1; 1-4294-1537-1
• Descrizione fisica: 1 online resource (447 p.)
• Collana: The international series of monographs on chemistry ; ; 31
• Altri autori (Persone): HaseWilliam L
• Disciplina: 541.3/93
• Soggetti: Unimolecular reactions; Chemistry
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Previously issued in print: 1996.
• Nota di bibliografia: Includes bibliographical references and indexes.
• Nota di contenuto: Contents; 1. Introduction; 2. Vibrational/Rotational Energy Levels; 3. Potential Energy Surfaces; 4. State Preparation and Intramolecular Vibrational Energy Redistribution; 5. Experimental Methods in Unimolecular Dissociation Studies; 6. Theory of Unimolecular Decomposition-The Statistical Approach; 7. Applications and Extensions of Statistical Theories; 8. Dynamical Approaches to Unimolecular Rates; 9. Product Energy Distributions; 10. The Dissociation of Small and Large Clusters; Appendix; Author Index; Subject Index
• Sommario/riassunto: The book provides a penetrating and comprehensive description of energy selected reactions from a theoretical as well as experimental point of view. It presents three major aspects of unimolecular reactions involving the preparation of the reactants in selected energy states, the rate of dissipation of the activated molecule, and the partitioning of the excess energy among the final products.