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Record Nr. |
UNINA9910146086103321 |
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Autore |
Denisov E. T (Evgeniĭ Timofeevich) |
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Titolo |
Handbook of free radical initiators [[electronic resource] /] / E.T. Denisov, T.G. Denisova, T.S. Pokidova |
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Pubbl/distr/stampa |
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Hoboken, N.J., : Wiley-Interscience, c2003 |
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ISBN |
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1-280-27268-6 |
9786610272686 |
0-470-30573-8 |
0-471-28183-2 |
0-471-72147-6 |
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Descrizione fisica |
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1 online resource (903 p.) |
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Altri autori (Persone) |
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DenisovaTaissa G |
PokidovaT. S (Tamara S.) |
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Disciplina |
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Soggetti |
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Radicals (Chemistry) |
Free radicals (Chemistry) |
Free radicals (Chemistry) - Mechanism of action |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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CONTENTS; Preface; Symbols and Abbreviations; 1 Mechanisms of Decomposition of Initiators; 2 Cage Effect; 3 Methods of Study of Initiator Decomposition and Free Radical Generation; 4 Dialkyl Peroxides and Hydroperoxides; 5 Diacyl Peroxides, Peroxy Esters, Polyatomic, and Organometallic Peroxides; 6 Organic Polyoxides; 7 Azo Compounds; 8 Compounds with weak C-C, N-N, C-N, and N-O Bonds; 9 Parabolic Model of Bimolecular Homolytic Reaction; 10 Bimolecular and Trimolecular Reactions of Free Radical Generation by Dioxygen; 11 Bimolecular Reactions of Free Radical Generation by Ozone |
12 Bimolecular Reactions of Hydroperoxides with Free Radical Generation13 Free Radical Generation by Olefins; 14 Initiation by Haloid Molecules and Nitrogen Dioxide; 15 Free Radical Generation by Reactions of Ions with Molecules; 16 Isomerization and Decomposition of Free Radicals; 17 Free Radical Abstraction Reactions; 18 Free Radical Reactions for Hydrogen Transfer and Substitution; 19 Free Radical Addition; 20 Recombination and Disproportionation of Free Radicals; |
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Sommario/riassunto |
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Free radical initiators-chemical molecules which easily decompose into free radicals-serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and HydroperoxidesDiacyl Peroxides, Peresters, and Organic PolyoxidesAzo-CompoundsBimolecular Re |
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