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Record Nr. |
UNINA9910144322203321 |
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Titolo |
Formation of bonds to C, Si, Ge, Sn, Pb . Part 2 [[electronic resource] /] / founding editor, J.J. Zuckerman ; editor, A.P. Hagen |
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Pubbl/distr/stampa |
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New York, N.Y., : VCH, c1989 |
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ISBN |
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1-282-30808-4 |
9786612308086 |
0-470-14524-2 |
0-470-14545-5 |
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Descrizione fisica |
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1 online resource (541 p.) |
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Collana |
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Inorganic reactions and methods ; ; 10/2 |
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Altri autori (Persone) |
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ZuckermanJ. J <1936-1987.> (Jerold J.) |
HagenA. P |
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Disciplina |
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Soggetti |
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Chemical kinetics - Effect of temperature on |
Inorganic compounds - Synthesis |
Electronic books. |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and indexes. |
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Nota di contenuto |
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Inorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 10; The Formation of Bonds to the Group-IVB Elements (C, Si, Ge, Sn, Pb) (Part 2); Formation of Bonds between Elements of Group IVB (C, Si, Ge, Sn, Pb) and Group IllB (B, Al, Ga, In, TI); Introduction; Formation of Carbon-Boron Bonds; Industrial Preparation of Boron Carbide.; Industrial Preparation of Boron-Carbide Powders.; Densification of Powders.; Laboratory Preparation of Boron Carbide (from the Elements or Boron Halides) |
by Direct Synthesis.by Reduction of BCI3 by H2 in the Presence of Carbon.; by Chemical Vapor Deposition (CVD).; by Reduction of Boric Anhydride at Low Temperatures.; by Plasma Synthesis.; by Physical Vapor Deposition (PVD).; Crystal Growth.; Boron Carbide Fibers.; from Boron Halides; by Reaction with More Polar Organometallics (Metal-Metal Exchange, Excluding Amino-, Oxo- and Thioboron Halides).; by Reaction with an Organoboron-Active-Metal Reagent.; by Substitution |
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of Hydrocarbons.; by Addition to Olefinic and Acetylenic Linkages (Haloboration).; by Reaction with Diazoalkanes. |
by Redistribution Reactions with Organoboranes.from Boron Alkoxides with More Polar Organometallics; Alkyl- and Arylboronic Acids.; Alkyl- and Arylborinic Acids.; to form Organoboranes with Three B-C Bonds.; from Boron Hyrides; by Addition to Olefins and Acetylenes (Hydroboration).; by Addition to Polar Organometallics to Form Organoborates.; by Redistribution of Organoboron Hydrides.; from Organoboranes; by Redistribution.; by lsomerization and Displacement.; by Pyrolytic Elimination of H2.; by Addition of Olefinic and Acetylenic Linkages (Carboboration).; from Larger Boranes and Carboranes |
by Hydroboration of a Polyborane.by Modified Metal Halide-Catalyzed Alkylations with Organic Halides at a Boron Site.; by B,B Addition of Polyboranes to Alkynes.; by Boron Hydrides with Acetylides, Cyanides, or lsocyanides.; by CO Displacements from Polyboranes.; by Other Reactions Using Polyboranes.; Formation of Carbon-Al Bonds; from the Elements; from Al Metal and Its Alloys; by the Interaction of H2 Olefin and Al Metal.; by the Action of Organic Halides on Al.; by the Reaction of Organomercurials with Al.; from Al Halides or Organoaluminum Halides; by Reaction with Polar Organometallics. |
by Redistribution with Organoaluminums.by the Interaction with an Active-Metal Hydride and Olefin.; by the Dehalogenation of RnAIX3- n with Active Metals.; from Al Hydrides or Complex Al Hydrides; by Addition to Olefins or Acetylenes (Hydroalumination).; by Transfer of Al Hydride from One Olefin to Another-Al Alkyl-Olefin Displacement.; by Redistribution with Organoaluminums.; by Exchange with Other Organometallics.; from Other Organoaluminum Compounds; by Addition of R-AI Bonds to Olefins or Acetylenes (Carbalumination). |
by Substitution of Acidic Carbon-Hydrogen Bonds by Carbon-Al Bonds (Alumination). |
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Sommario/riassunto |
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For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifiying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulne |
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