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Record Nr. |
UNINA9910144314803321 |
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Titolo |
Inorganic syntheses . Volume XIII / / editor-in-chief, F.A. Cotton |
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Pubbl/distr/stampa |
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New York, : McGraw Hill, 1971 |
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ISBN |
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9786612305511 |
9781282305519 |
1282305514 |
9780470132449 |
0470132442 |
9780470132791 |
0470132795 |
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Descrizione fisica |
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1 online resource (288 p.) |
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Collana |
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Inorganic syntheses ; ; 13 |
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Altri autori (Persone) |
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CottonF. Albert <1930-2007.> (Frank Albert) |
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Disciplina |
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Soggetti |
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Inorganic compounds - Synthesis |
Chemistry, Inorganic |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and and index. |
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Nota di contenuto |
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INORGANIC SYNTHESES; CONTENTS; Preface; Notice to Contributors; Chapter One COMPOUNDS OF THE NONTRANSITION ELEMENTS; 1. Perbromic Acid and Potassium Prebromate; 2. a-Sulfanuric Chloride-Cyclic Trimer; A. (Trichlorophosphoranylidene)sulfamoyl Chloride; B. a-Sulfanuric Chloride-Cyclic Trimer; 3. Arsine and Arsine-d3; 4. Ammonium Cyanate; 5. Phosphorus(III) Isocyanate; 6. Phosphoramidic Acid and Its Salts; A. Ammonium Hydrogen Phosphoramidate; B. Phosphoramidic Acid; C. Potassium Hydrogen Phosphoramidate; 7. Diphenyl(trimethylsilyl)phosphine and DimethyI(trimethylsilyl)phosphine |
A. Diphenyl(trimethylsilyl)phosphineB. Dimethyl(trimethylsilyl)phosphine; 8. Exchange Reactions for the Syntheses of Phenylboron Chlorides and Tetrafluoromethylphosphorane; A. Dichloro(phenyl)borane, C6H5BCl2; B. Chlorodiphenylborane, (C6H5)2BCl; C. Tetrafluoromethylphosphorane, CH3PF4; 9. 2,4,6-Trichloroborazine; 10. 2,4,6-Trichloro-1,3,5-trimethylboraeine; Chapter Two |
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ORGANOMETALLIC COMPOUNDS; 11. Cyclic-diolefin Complexes of Platinum and Palladium; A. Platinum Compounds; B. Palladium Compounds; 12. Cationic Diene Complexes of Palladiuni(II) and Platinum(II); A. Complexes of Type (I) |
B. Complexes of Type (II)C. Complexes of Type (III); D. Complexes of Type (IV); 13. Trichloro-, Trimethyl-, and Trifluorosilylcobalt Tetracarbonyl; A. Tetracarbonyl(trichlorosilyl)cobalt; B. Tetracarbonyl(trimethylsilyl)cobalt; C. Tetracarbonyl(trifluorosilyl)cobalt; 14. Isoleptic Allyl Derivatives of Various Metals; A. Allyl Magnesium Chloride; B. Tetraallylstannane; C. Tetraallylsilane and Tetraallylgermane; D. Tri-h3-allylchromium; E. Di-h3-allylnickel; Chapter Three COMPOUNDS CONTAINING METAL-TO- METAL BONDS; 15. Rhenium and Molybdenum Compounds Containing Quadruple Bonds |
A. Octahalodirhenate(III) AnionsB. Tetrakis(carboxylato)dihalodirhenium(III) Compounds; C. Tetrakis(carboxylato)dimolyndenum (II) Compounds; 16. Tetrakis(acetato)dirhodium(II) and Similar Carboxylato Compounds; 17. Dodecacarbonyltriruthenium and -triosmium; A. Dodecacarbonyltriruthenium; B. Dodecacarbonyltriosmiuin; 18. Dodecacarbonyltetrairidium; 19. Disodium Hexaalkoxy-octa-u3-chloro-hexamolybdates; A. Disodium Octa-u3-chloro-hexaniethoxyhexamolybdate(II); B. Disodium Octa-u3-chloro-hexaethoxyhexamolybdate(II); C. Disodium Octa-u3-chloro-hexamolybdate(II) |
Chapter Four PHOSPHINE AND PHOSPHITE COMPLEXES OF LOW-VALENT METALS20. Triaryl Phosphite Complexes of Cobalt, Nickel. Platinum. and Rhodium; A. Hydridotetrakis(triphenyl phosphite)cobalt(I); B. Tetrakis(triphenyl phosphite)nickel(0); C. Tetrakis(triphenyl phosphite)platinum(0); D. Hydridotetrakis(triphenyl phosphite)rhodium(I); 21. Tetrakis(triethyl phosphite)nickel(0), Palladium(0), and Platinum(0) Complexes; A. Tetrakis(triethyl phosphite)nickel(0); B. Tetrakis(triethyl phosphite)palladium(0); C. Tetrakis(triethyl phosphite)platinum(0); D. Tetrakis(triphenyl phosphite)nickel(0) |
22. Low-valent Metal Complexes of Diethyl Phenylphosphonite |
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Sommario/riassunto |
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The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested. |
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