1.

Record Nr.

UNINA9910144313703321

Titolo

Inorganic syntheses . Volume XVII [[electronic resource] /] / editors, Aaron Wold, John K. Ruff

Pubbl/distr/stampa

New York, : McGraw Hill, 1977

ISBN

1-282-30595-6

9786612305955

0-470-13248-5

0-470-13283-3

Descrizione fisica

1 online resource (238 p.)

Collana

Inorganic syntheses ; ; 17

Altri autori (Persone)

WoldAaron <1927->

RuffJohn K

Disciplina

541.39

541/.39

Soggetti

Inorganic compounds - Synthesis

Chemistry, Inorganic

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and and index.

Nota di contenuto

INORGANIC SYNTHESES Volume XVII; CONTENTS; Preface; Notice to Contributors; Chapter One METAL HYDRIDES; I. MAIN GROUP HYDRIDES (E. C. Ashby); 1. Magnesium Dihydride; 2. Zinc Dihydride; 3. Lithium Trihydridozincate(1-) and Lithium Tetrahydridozincate(2-); A. Lithium Trihydridozincate(1-); B. Lithium Tetrahydridozincate(2-); 4. Sodium Trihydridodimethyldizincate(1-) and Sodium Trihydridozincate(1-); A. Sodium Trihydridodimethyldizincate(1-); B. Sodium Trihydridozincate(1-); 5. Calcium Bis[tetrahydroborate(1-)]; 6. Quaternary Ammonium and Phosphonium Heptahydroborates

A. Methyltriphenylphosphonium Tetrahydroborate(1-)B. Tetrabutylammonium Tetrahydroborate(1-); C. Methyltriphenylphosphonium Heptahydrodiborate(1-); D. Tetrabutylammonium Heptahydrodiborate(1-); 7. Potassium Tri(sec-butyl)hydroborate(l-); 8. Bis(dimethylamino)borane; 9. Bis-u-(dimethylamino)-diborane(6); 10. u-(Dimethylamino)-diborane(6); 11. Trihydrido(trimethy1amink)aluminum and (Diethy1amino)hydridoaluminum Complexes; A. Triliydrido(trimethylamine)aluminum;



B. (Diethylamino)dihydridoaluminum; C. Bis(diethylarnino)hydridoaluminum; 12. Trihydrido(trimethylarnine)galliurn

13. Lithium Tetrahydridogallate(1-)14. Sodium and Potassium Tetrahydridogallate(1-); II. TRANSITION METAL HYDRIDE COMPLEXES (Herbert D. Kaesz); 15. Hydrido Phosphine Arene Complexes of Molybdenum; A. Bis(n6-benzene)molybdenum; B. (n6-Benzene)dihydridobis(triphenylphosphine)molybdenum; C. (n6-Benzene)tris(dimethylphenylphosphine)hydridomolybdenum Hexafluorophosphate(1-); D. (n6-Benzene)tris(dimethylphenylphosphine)dihydridomolybdenum Bis[hexafluorophosphate(1-)]; 16. Bis[ethylenebis(diphenylphosphine)]hydrido(2,4-pentanedionato)molybdenum(II)

17. Tris(dimethylphenylphosphine)pentahydridorhenium(V)18. Dodecacarbonyltri-p-hydrido-triarigulo-trirhenium(I); 19. Bis[ethylenebis(diphenylphosphine)]hydridoiron Complexes; A. Chlorobis[ethylenebis(diphenylphosphine)]hydridoiron(II); B. Bis[ethylenebis(diphenylphosphine)]hydridoiron(II) Tetraphenylborate(1-); C. Bis[ethylenebis(diphenylphosphine)]hydridoiron(I); 20. Hydridonitrosyltris(triphenylphosphine)ruthenium(I); 21. Dihydridotetrakis(triphenylphosphine)ruthenium(II); 22. Hydrido[(n6-phenyl)diphenylxsphosphine]bis(triphenylphosphine)ruthenium(II) Tetrafluoroborate(1-)

23. (Acetato)hydridotris(triphenylphosphine)ruthenium(II)24. Hydridobis[(+)-dioplrhodium(1); 25. Nickel and Palladium Chlorohydridobis(phosphine) Complexes; A. trans-[Chlorohydridobis(tricyclohexylphosphine)nickel]; B. trans-[Chlorohydridobis(triisopropylphosphine)nickel]; C. trans-[Chlorohydridobis(tricyclohexylphosphine)palladium]; 26. Hydrido[tetrahydroborato(1-)] Nickel and Palladium Complexes; A. trans-[Hydrido[tetrahydroborato(1-)]bis(tricyclohexylphosphine)nickel]; B. trans-[Hydrido[tetrahydroborato(1-)]bis(tricyclohexylphosphine)palladium]

27. Bis(n5-cyclopentadienyl)[tetrahydroborato(1-)]titanium

Sommario/riassunto

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.