1.

Record Nr.

UNINA9910144312303321

Titolo

Inorganic syntheses . Volume 22 [[electronic resource] /] / editor-in-chief, Smith L. Holt, Jr

Pubbl/distr/stampa

New York, : McGraw Hill, 1983

ISBN

1-282-30540-9

9786612305405

0-470-13253-1

0-470-13288-4

Descrizione fisica

1 online resource (298 p.)

Collana

Inorganic syntheses ; ; 22

Altri autori (Persone)

HoltSmith L. <1938->

Disciplina

541.39

541/.39

Soggetti

Inorganic compounds - Synthesis

Chemistry, Inorganic

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and and index.

Nota di contenuto

INORGANIC SYNTHESES Volume 22; CONTENTS; Chapter One SOLID STATE; 1. Ternary Chlorides and Bromides of the Rare Earth Elements; A. AIRE2IIIX7: Cesium Praesodymium Chloride (CsPr2Cl7) and Postassium Dysprosium Chloride (KDy2Cl7); B. AI3RE2IIIX9, AI2REIIIX5, AI3REIIX6: The Cesium Lutetium Chlorides, Cs3Lu2Cl9, Cs2LuCl5, Cs3LuCl6; 2. Quaternary Chlorides and Bromides of the Rare Earth Elements: Elpasolites AI2BIREIIIX6 (r(AI)>r(BI)); A. Cesium Lithium Thulium Chloride, (Cs2LiTmCl6); B. Other Chloro- and Bromo elpasolites; 3. Tantalum as a High-Temperature Container Material for Reduced Halides

4. Cesium Scandium(II) TrichlorideA. Synthesis with CsCl; B. Synthesis with Cs3Sc2Cl9; 5. Zirconium Monochloride and Monobromide; A. Synthesis with Zirconium Foil; B. Synthesis Using Zirconium Turnings; 6. Lanthanum Triiodide (And Other Rare Earth Metal Triiodides); A. Synthesis Using Hgl2; B. Synthesis from the Elements; 7. Lanthanum Diiodide; 8. Trichlorides of Rare Earth Elements. Yttrium, and Scandium; 9. Single Crystal Growth of Oxides by Skull Melting: The Case of Magnetite (Fe3O4; 10. Lithium Nitride, Li3N; A. Polycrystalline



Material; B. Single Crystals of Li3N

11. The Alkali Ternary Oxides AXCoO2 and AXCrO2 (A = Na, K)A. Sodium Cobalt Oxides: NaxCoO2 (x < 1); B. Potassium Cobalt Oxide Bronzes: K0.50CoO2, K0.67CoO2; C. Potassium Cobalt Oxide: KCoO2; D. Potassium Chromium Oxide: KCrO2; E. Potassium Chromium Oxide Bronzes: KxCrO2; 12. Zeolite Molecular Sieves; A. Zeolite A2; B. Zeolite Y3; C. TMA Offretite4; D. ZSM-5; 13. Lead Ruthenium Oxide, Pb2 [Ru2-xPb4x+]O6.5; 14. Calcium Manganese Oxide. Ca2Mn3O8; 15. Synthesis of Silver Tetratungstate; 16. Cadmium Mixed Chalcogenides and Layers of Cadmium (Mixed); A. Cadmium Selenide Telluride (CdSe0.65Te0.35)

B. Cadmium Selenide Thin Layers on TitaniumC. Cadmium Selenide Telluride Layers on Molybdenum; 17. Layered Intercalation Compounds; A. Charge-Transfer-Type Intercalation Compounds: FeOCl(Pyridine derivative)1/n; B. Grafted-Type Compound from FeOCl; C. The Organic Intercalates of HTiNbO5; 18. Iron Titanium Hydride (FeTiH1.94); 19. Aluminum Lanthanum Nickel Hydride; Chapter Two TRANSITION METAL COMPLEXES AND COMPOUNDS; 20. Purification of Copper(I) Iodide; 21. Cobalt(III) Amine Complexes with Coordinated Trifluoromethanesulfonate

A. Pentammine(trifluoromethanesulfonato)cobalt(III) Trifluoromethanesulfonate, [Co(NH3)5OSO2CF3](CF3SO3)2B. cis-Bis(1,2-ethylenediarnine)di(trifluoromethanesulfonato )- cobalt(III) Trifluoromethanesulfonate, cis-[Co(en2)(OSO2CF3)2](CF3SO3); C. fac-Tris(trifluoromethanesulfonato)[N-(2-aminoethyl)-1,2-ethanediamine]cobalt(III), Co(dien)(OSO2CF3)3; 22. 2,9-Dimethyl-3,10-diphenyl-1,4,8,11-tetraazacyclotetradeca-1,3,8,10-tetraene, (Me2Ph2 [14]-1,3,8,10-tetraeneN4) Complexes

A. Bis(acetonitrile)(2,9-dimethyl-3,10-diphenyl-1,4,8,11-tetraazacyclotetradeca-1,3,8,10-tetraene)iron(II) Hexafluorophosphate



2.

Record Nr.

UNISA996204916703316

Titolo

Colloid science [[electronic resource] ] : principles, methods and applications / / edited by Terence Cosgrove

Pubbl/distr/stampa

Oxford, UK ; ; Ames, Iowa, : Blackwell Pub., 2010

ISBN

1-4443-2020-3

1-282-54817-4

1-281-21483-3

9786611214838

9786612548178

0-470-76152-0

1-4443-0539-5

1-4051-6838-2

Edizione

[2nd ed.]

Descrizione fisica

1 online resource (399 p.)

Altri autori (Persone)

CosgroveT (Terence)

Disciplina

541.345

541/.345

Soggetti

Colloids

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Colloid Science Principles, methods and applications; Contents; Preface; Introduction; Acknowledgements; List of Contributors; 1 An Introduction to Colloids; 1.1 Introduction; 1.2 Basic Definitions; 1.2.1 Concentration; 1.2.2 Interfacial Area; 1.2.3 Effective Concentrations; 1.2.4 Average Separation; 1.3 Stability; 1.3.1 Quiescent Systems; 1.3.2 Sedimentation or Creaming; 1.3.3 Shearing Flows; 1.3.4 Other Forms of Instability; 1.4 Colloid Frontiers; References; 2 Charge in Colloidal Systems; 2.1 Introduction; 2.2 The Origin of Surface Charge; 2.2.1 Ionisation of Surface Groups

2.2.2 Ion Adsorption2.2.3 Dissolution of Ionic Solids; 2.2.4 Isomorphous Substitution; 2.2.5 Potential Determining Ions; 2.3 The Electrochemical Double Layer; 2.3.1 The Stern-Gouy-Chapman (SGC) Model of the Double Layer; 2.3.2 The Double Layer at the Hg/Electrolyte Interface; 2.3.3 Specific Adsorption; 2.3.4 Interparticle Forces; 2.4 Electrokinetic Properties; 2.4.1 Electrolyte Flow; 2.4.2



Streaming Potential Measurements; 2.4.3 Electro-osmosis; 2.4.4 Electrophoresis; 2.4.5 Electroacoustic Technique; References; 3 Stability of Charge-stabilised Colloids; 3.1 Introduction

3.2 The Colloidal Pair Potential3.2.1 Attractive Forces; 3.2.2 Electrostatic Repulsion; 3.2.3 Effect of Particle Concentration; 3.2.4 Total Potential; 3.3 Criteria for Stability; 3.3.1 Salt Concentration; 3.3.2 Counter-ion Valency; 3.3.3 Zeta Potential; 3.3.4 Particle Size; 3.4 Kinetics of Coagulation; 3.4.1 Diffusion-limited Rapid Coagulation; 3.4.2 Interaction-limited Coagulation; 3.4.3 Experimental Determination of c.c.c.; 3.5 Conclusions; References; 4 Surfactant Aggregation and Adsorption at Interfaces; 4.1 Introduction; 4.2 Characteristic Features of Surfactants

4.3 Classification and Applications of Surfactants4.3.1 Types of Surfactants; 4.3.2 Surfactant Uses and Development; 4.4 Adsorption of Surfactants at Interfaces; 4.4.1 Surface Tension and Surface Activity; 4.4.2 Surface Excess and Thermodynamics of Adsorption; 4.4.3 Efficiency and Effectiveness of Surfactant Adsorption; 4.5 Surfactant Solubility; 4.5.1 The Krafft Temperature; 4.5.2 The Cloud Point; 4.6 Micellisation; 4.6.1 Thermodynamics of Micellisation; 4.6.2 Factors Affecting the CMC; 4.6.3 Structure of Micelles and Molecular Packing; 4.7 Liquid Crystalline Mesophases; 4.7.1 Definition

4.7.2 Structures4.7.3 Phase Diagrams; 4.8 Advanced Surfactants; References; 5 Microemulsions; 5.1 Introduction; 5.2 Microemulsions: Definition and History; 5.3 Theory of Formation and Stability; 5.3.1 Interfacial Tension in Microemulsions; 5.3.2 Kinetic Instability; 5.4 Physicochemical Properties; 5.4.1 Predicting Microemulsion Type; 5.4.2 Surfactant Film Properties; 5.4.3 Phase Behaviour; 5.5 Developments and Applications Temperature; 5.5.1 Microemulsions with Green and Novel Solvents; 5.5.2 Microemulsions as Reaction Media for Nanoparticles; References; 6 Emulsions; 6.1 Introduction

6.1.1 Definitions of Emulsion Type

Sommario/riassunto

Colloidal systems are important across a range of industries, such as the food, pharmaceutical, agrochemical, cosmetics, polymer, paint and oil industries, and form the basis of a wide range of products (eg cosmetics & toiletries, processed foodstuffs and photographic film). A detailed understanding of their formation, control and application is required in those industries, yet many new graduate or postgraduate chemists or chemical engineers have little or no direct experience of colloids. Based on lectures given at the highly successful Bristol Colloid Centre Spring School, Colloid Scie