1.

Record Nr.

UNINA9910144310403321

Autore

Pirrung Michael C

Titolo

The total synthesis of natural products . Volume 10 A sesquidecade of sesquiterpenes: total synthesis, 1980-1994 . Part A Acyclic and monocyclic sesquiterpenes [[electronic resource] /] / Michael C. Pirrung and Andrew T. Morehead, Jr.; edited by David Goldsmith

Pubbl/distr/stampa

New York, : Wiley, 1997

ISBN

1-282-30584-0

9786612305849

0-470-12973-5

0-470-12962-X

Descrizione fisica

1 online resource (194 p.)

Collana

The total synthesis of natural products ; ; 10

Altri autori (Persone)

MoreheadAndrew T

GoldsmithDavid

Disciplina

547 /.2

547.70459

Soggetti

Terpenes

Sesquiterpenes

Electronic books.

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

THE TOTAL SYNTHESIS OF NATURAL PRODUCTS; CONTENTS; Acknowledgments; Introduction; Reagent Glossary; I . ACYCLIC SESQUITERPENES; A. Farnesene, Farnesol, Terrestrol; B. Nerolidol, 5,8-Dehydro-4-oxonerolidol; C. Sesquilavandulol; D. Solanone; E. Sinensals; F Juvenile Hormones; G. 2,5,9-Trimethyl-2-vinyl-deca-4,8-dienal, (E)-6,10-Dimethyl-9-methylene-undec-5-en-2-one; H. Dendrolasin, Sesquirosefuran, Freelingnite, Dehydrolasiosperman, Dehydromyopyrone, (R)-Myopyrone, Pleraplysillin-2, Siphonidictidine; I. Ipomeamarone, Davanone, Artemone, Athanasin; References; II. MONOCYCLIC SESQUITERPENES

A. Aromatic Bisabolenes1. a-Curcumene, iso-a-Curcumene, ar-Turmerone; 2. Nuciferol, Nuciferal; 3. Curcuquinone, Curcuphenols, Curcudiol, Perezones, Xanthorrhizol; 4. ar-Todomatuic Acid, ar-Juvabione, Elvirol, Sydonic Acid; 5. Hellianuol A, Furoixiolal; B.



Bisabolenes; 1. a-Bisabolene, B-Bisabolene, y-Bisabolenes; 2. Epoxy-a-bisabolene, Bisabol- 10-ene-3,7-oxide, y-Bisabolene-8,9-oxide, 4,5-Dihydro-B-curcumen-4,5-diol; 3. a-Bisabolol, B-Bisabolol, a-Atlantone, B-Atlantone; 4. Aminobisabolene, Theonellin Isocyanide, 8-Desoxyisocaespitol

5. Zingiberenol, B-Sesquiphellandrene, Bilobanone, Bisabolangelone, Lanceol6. Hernandulcin; 7. Juvabiols, Juvabione; 8. Paniculides; 9. Phyllanthocin, Phyllanthocindiol, Phyllanthoside; C. Elemanes; 1. B-Elemene, y-Elemene, a-Elemene, B-Elemol, B-Elemenone; 2. Shyobunone, Curzurenones; 3. Melitensin, Deoxymelitensin, Temisin, Saussurea Lactone; 4. Zempoalins, Callitrin, Igalan, Isogermafurenolide, Isofuranogermacrene, Hydroxyisogermafurenolide, Desoxysericealactone, and Unnamed 8,12-Elemanolides; 5. Vernolepin; D. Peroxidic Antimalarials; 1. Qinghaosu (Artemisinin), Yingzhaosu A, Yingzhaosu C

E. Cyclocitrals1. Deoxytrisporone, (E)-3-Formyl-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenal, 4-(2,2,6-trimethyl-6-vinylcyclohexyl)-2-butanone; 2. Caparappi Oxide, Dactyloxene-B and -C, Ancistrofuran, Ricciocarpin; 3. Pallescensin 1, Penlanpallescensin; 4. Snyderols, Aplysistatin, Palisadins; F. Secoeudesmanes; 1. Phytuberin; 2. Eriolanin, Eriolangin; 3. Tridensone, Umbellifolide; G. Germacranes; 1. Germacrene-D, Bicyclogermacrene, Isobicyclogermacrenal; 2. Hedycaryol, Acoragermacrone, Germacrone

3. Costunolide, Dihydrocostunolide, Haageanolide, Isabelin, Eucannabinolide, 4,5-cis-3b-Hydroxygermacranolide, Aristolactone4. Linderalactone, Neolinderalactone, Sericenine; 5. Periplanones; H. Miscellaneous Monocarbocyclic Sesquiterpenes; 1. Humulene, Zerumbone, Bicyclohumulenone; 2. Furoventalene, Pleraplysillin-1; 3. Myodesmone, Myomontanone, Lactaral; 4. Hanegokedial, Heptelidic Acid, Ovalicin; 5. Curcumanolide A, Isocanambrin; 6. Methyl Acorate, Secocrispiolide; 7. Himasecolone, Methyl Nidorellaurinate, Sesquichamaenol, 3-Methyl-5-(2,3,6-trimethylphenyl)-1-penten-3-ol

8. Karatavic Acid, Cabreuva Oxides, Isohumbertiols, Chokol C

Sommario/riassunto

The indispensable reference for the twenty-first century chemist...A fascinating and comprehensive look into one of chemistry's fastest growing specialties--sesquiterpene synthesis--Volume Ten of The Total Synthesis of Natural Products focuses on acyclic and monocyclic compounds and sheds light on the structure and makeup of this important class of hydrocarbons.A useful and practical tool for researchers interested in locating any of the major classes of sesquiterpene compounds, the author will also provide, if needed, a database to the more than 1,600 articles on sesquiterpene