1.

Record Nr.

UNINA9910144309803321

Titolo

Organic reaction mechanisms [[electronic resource] ] . 1969 : an annual survey covering the literature dated December 1968 through November 1969 / / edited by B. Capon, C. W. Rees

Pubbl/distr/stampa

London, : Interscience Publishers, 1970

ISBN

9786612112492

9781282112490

128211249X

9780470318911

0470318910

9780470318928

0470318929

Descrizione fisica

1 online resource (725 p.)

Collana

Organic Reaction Mechanisms Series ; ; v.109

Altri autori (Persone)

CaponB

ReesCharles W (Charles Wayne)

Disciplina

547.139

547.2

Soggetti

Chemistry, Organic

Chemistry

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Includes indexes.

Nota di contenuto

ORGANIC REACTION MECHANISMS  1969; Contents; Carbonium Ions; Bicyclic and Polycyclic Systems; Participation by Aryl Groups; Participation by Double and Triple Bonds; Reactions of Small-ring Compounds; Metallocenylmethyl Cations; Other Stable Carbonium Ions and their Reactions; Nucleophilic Aliphatic Substitution; Ion-pair Phenomena and Borderline Mechanisms; Solvent and Medium Effects; Isotope Effects; Neighbouring Group Psrticipation; Deamination and Related Reactions; Reactions of Aliphatic Diazo-compounds; Fragmentation Reactions; Displacement Reactions at Elements other than Carbon

Ambident NucleophilesSubstitution at Vinylic Carbon; Reactions of a-Halogenocarbony1 Compounds; Other Reactions; Carbanions and Electrophilic Aliphatic Substitution; Carbanion Structure and Stability;



Reactions of Carbanions; Proton Transfer, Hydrogen Isotope Exchange, and Related Reactions; Organometallics: Groups Ia, IIa, III; Organometallics: Other Elements; Electrophilic Reactiom of Hydrocarbons; Miscellaneous Reactions; Elimination Reactions; Steric Course of E2 Reactions; Orientation in E2 Reactions; The ElcB Mechanism; Other Topics; Addition Reactions; Electrophilic Additions

Nucleophilic AdditionsCycloadditions; Nucleophilic Aromatic Substitution; The SNAr Mechanism; Heterocyclic Systems; Meisenheher and Related Complexes; Substitution in Polyhalogenoammatic Compounds; Other Reactions; Benzyne and Related Intermediafes; Electrophilic Aromatic Substitution; Sulphomtion; Nitration and Nitrosation; Azo Coupling; Friedel-Crafts and Related Reactions; Halogenation; Hydrogen Exchange; Metalation; Metal Cleavage; Decarboxylation; Miscellaneous Reactions; Molecular Rearrangements; Aromatic Rearrangements; Further Sigmatropic Migrations; Small-ring Rearrangements

Other Eleotrocyclic ReactionsHeterocyclic Rearrangements; Other Rearrangements; Radical Reactions; Structure and Stereochemistry; Decomposition of Azo-compounds and Peroxides; Diradicals; Atom- transfer Processes; Additions; Aromatic Substitution; Rearrangements; Reactions Involving Oxidation or Reduction by Metal Salts; Nitroxides; Reactions Involving Radical Ions; Electrochemical Processes; Autoxidation; Miscellaneous; Carbenes and Nitrenes; Structure; Methods of Generation; Insertions and Abstractions; Cycloaditions; Rearrangements and Fragmentations

Reactions with Nucleophiles and ElectrophilesCarbenoids and Metal Complexes; Reactions of Aldehydes and Ketones and their Derivatives; Formation and Reactions of Acetals and Ketals; Hydrolysis and Formation of Glycosides; Hydration of Aldehydes and Ketones and Related Reactions; Reactions with Nitrogen Bases; Hydrolysis of Enol Ethers and Ester; Enolization and Related Reactions; Aldol Reaction; Reactions of Enamines; Other Reactions; Reactions of Acids and their Derivatives; CarboxyIic Acids; Non-carboxylic Acids; Photochemistry; Physical Aspects; Carbonyl Compounds; Acid Derivatives

Olefins

Sommario/riassunto

This annual series on organic reaction mechanisms research provides concise, comprehensive coverage of the year's literature as well as discussions of important results. The present volume either discusses or lists all published work dated from December to November inclusive, that deals significantly with any aspect of organic reaction mechanisms.