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Record Nr. |
UNINA9910144298203321 |
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Autore |
Vorbrüggen Helmut |
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Titolo |
Silicon-mediated transformations of functional groups [[electronic resource] /] / Helmut Vorbrüggen |
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Pubbl/distr/stampa |
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Weinheim, : Wiley-VCH, c2004 |
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ISBN |
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1-280-52080-9 |
9786610520800 |
3-527-60377-8 |
3-527-60592-4 |
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Descrizione fisica |
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1 online resource (378 p.) |
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Disciplina |
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Soggetti |
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Functional groups |
Silicon |
Electronic books. |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and indexes. |
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Nota di contenuto |
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Silicon-mediated Transformations of Functional Groups; Contents; Preface; 1 Introduction; 2 Techniques for Preparative Silylations-Desilylations; 3 Preparation and Properties of Silyloxy Leaving Groups; 4 Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide; 5 Reactions of Aldehydes and Ketones; 6 Reactions of Alcohols, Esters, Silyl Ethers, Epoxides, and Haloalkanes; 7 Reactions of N-O Systems; 8 Reactions of S-O and Se-O Systems; 9 Cyclizations and Ring Enlargements; 10 Base-catalyzed, Acid-catalyzed and Thermal Eliminations of Trimethylsilanol. Peterson Reactions |
11 Formation of Carbon-Phosphorus Double Bonds12 Reductions and Oxidations; 13 Dehydration-Halogenation-Activation and Silylation of Inorganic and Organic Salts and Metallorganic Compounds; 14 Formation of Organic and Inorganic Polymers; Appendix; Subject Index; Author Index |
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Sommario/riassunto |
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In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbr?ggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar |
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