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Record Nr. |
UNINA9910140266403321 |
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Titolo |
Inorganic syntheses . Volume 36 / / [edited by] Gregory S. Girolami, Alfred P. Satterberger |
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Pubbl/distr/stampa |
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Hoboken, New Jersey : , : John Wiley & Sons, , 2014 |
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©2014 |
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ISBN |
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1-118-74484-5 |
1-118-74499-3 |
1-118-74496-9 |
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Descrizione fisica |
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1 online resource (333 p.) |
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Collana |
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Disciplina |
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Soggetti |
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Inorganic compounds - Synthesis |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and indexes. |
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Nota di contenuto |
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Inorganic Syntheses; Preface; Dedication; Notice to Contributors and Checkers; Toxic Substances and Laboratory Hazards; Contents; Chapter One: Transition Metal Halide Compounds; 1. Octahedral Hexatantalum Halide Clusters; A. Tetradecachlorohexatantalum Octahydrate; B. Tetradecabromohexatantalum Octahydrate; C. Tetrakis(benzyltributylammonium) Octadecachlorohexatantalate; 2. Octahedral Hexamolybdenum Halide Clusters; A. Tetradecachlorohexamolybdate Hexahydrate (Chloromolybdic Acid); B. Hexamolybdenum Dodecachloride; 3. Ether Complexes of Molybdenum(III) and Molybdenum(IV) Chlorides |
A. Tetrachlorobis(diethyl ether)molybdenum(IV)B. Trichlorotris(tetrahydrofuran)molybdenum(III); 4. Octahedral Hexatungsten Halide Clusters; A. Bis(hydroxonium) Tetradecachlorohexatungstate Heptahydrate (Chlorotungstic Acid); B. Hexatungsten Dodecachloride; 5. Trinuclear Tungsten Halide Clusters; A. Tritungsten Decachloride; B. Trisodium Tridecachlorotritungstate; C. Tris(benzyltributylammonium) Tridecachlorotritungstate; 6. Crystalline and Amorphous Forms of Tungsten Tetrachloride; A. Crystalline Tungsten Tetrachloride by Solid-State Reduction |
B. Amorphous Tungsten Tetrachloride by Solution-Phase ReductionChapter Two: Cyclopentadienyl Compounds; 7. Sodium and |
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Potassium Cyclopentadienide; A. Sodium Cyclopentadienide; B. Potassium Cyclopentadienide; 8. (Pentafluorophenyl)cyclopentadiene and its Sodium Salt; A. (Pentafluorophenyl)cyclopentadiene; B. Sodium (Pentafluorophenyl)cyclopentadienide; 9. Bis(η5-pentamethylcyclopentadienyl) Complexes of Scandium; A. Bis(η5-pentamethylcyclopentadienyl)chloroscandium; B. Bis(η5-pentamethylcyclopentadienyl)methylscandium; C. Bis(η5-pentamethylcyclopentadienyl)phenylscandium |
D. Bis(η5-pentamethylcyclopentadienyl)(o-tolyl)scandium10. Bis(η5-pentamethylcyclopentadienyl) Complexes of Titanium,Zirconium, and Hafnium; A. Bis(η5-pentamethylcyclopentadienyl)dichlorotitanium(IV); B. Bis(η5-pentamethylcyclopentadienyl)dichlorozirconium(IV); C. Bis(η5-pentamethylcyclopentadienyl)dichlorohafnium(IV); 11. Bis(η5-pentamethylcyclopentadienyl) Complexes of Niobiumand Tantalum; A. Bis(η5-pentamethylcyclopentadienyl)dichlorotantalum(IV); B. Bis(η5-pentamethylcyclopentadienyl)dichloroniobium(IV); 12. Bis(η5-pentamethylcyclopentadienyl) Complexes of Molybdenum |
A. Bis(pentamethylcyclopentadienyl)dichloromolybdenum(IV)B. Bis(pentamethylcyclopentadienyl)dihydridomolybdenum(IV); 13. (η5-Cyclopentadienyl)tricarbonylmanganese(I) Complexes; A. (η5-Cyclopentadienyl)tricarbonylmanganese(I); B. (η5-Pentamethylcyclopentadienyl)tricarbonylmanganese(I); 14. 1,1'-Diaminoferrocene; A. 1,1'-Dilithioferrocene N,N,N',N'-Tetramethylethylenediamine; B. 1,1'-Dibromoferrocene; C. One-Pot Preparation of 1,1'-Dibromoferrocene from Ferrocene; D. 1,1'-Diaminoferrocene; E. 1,1'-Diaminoferrocenium Hexafluorophosphate; F. 1,1'-Diaminoferrocenium Triflate |
15. Mono(η5-pentamethylcyclopentadienyl) Complexes of Osmium |
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Sommario/riassunto |
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This volume of Inorganic Syntheses spans the preparations of wide range of important inorganic, organometallic and solid-state compounds. The volume is divided into 6 chapters. The first chapter contains the syntheses ofsome key early transition metal halide clusters and the very useful mononuclear molybdenum(III) synthon, MoCl3(THF)3. Chapter 2 covers the synthesis of a number of cyclopentadienyl compounds, including a novel route to sodium and potassium cyclopentadienide, MC5H5. Chapter 3 details synthetic procedures for a range of m |
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