Polymeric chiral catalyst design and chiral polymer synthesis [[electronic resource] /] / edited by Shinichi Itsuno

• Record Nr.: UNINA9910139624803321
• Pubbl/distr/stampa: Hoboken, N.J., : Wiley, c2011
• ISBN: 1-283-17593-2; 9786613175939; 1-118-06395-3; 1-118-06396-1; 1-118-06394-5
• Descrizione fisica: 1 online resource (528 p.)
• Altri autori (Persone): ItsunoShinichi
• Disciplina: 668.9
• Soggetti: Enantioselective catalysis; Polymerization; Chirality
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: POLYMERIC CHIRAL CATALYST DESIGN AND CHIRAL POLYMER SYNTHESIS; CONTENTS; PREFACE; FOREWORD; CONTRIBUTORS; 1 AN OVERVIEW OF POLYMERIMMOBILIZED CHIRAL CATALYSTS AND SYNTHETIC CHIRAL POLYMERS; 1.1 INTRODUCTION; 1.2 POLYMERIC CHIRAL CATALYST; 1.2.1 Polymers Having a Chiral Pendant Group; 1.2.2 Main-Chain Chiral Polymers; 1.2.3 Dendrimer-Supported Chiral Catalysts; 1.2.4 Helical Polymers; 1.2.5 Multicomponent Asymmetric Catalysts; 1.2.6 Continuous Flow System; 1.3 SYNTHESIS OF OPTICALLY ACTIVE POLYMERS; 1.3.1 Asymmetric Reaction on Polymer; 1.3.2 Helical Polymers and Hyperbranched Polymers; 1.3.3 Heteroatom Chiral Polymers1.3.4 Asymmetric Polymerization; REFERENCES; 2 POLYMER-IMMOBILIZED CHIRAL ORGANOCATALYST; 2.1 INTRODUCTION; 2.2 SYNTHESIS OF POLYMER-IMMOBILIZED CHIRAL ORGANOCATALYST; 2.3 POLYMER-IMMOBILIZED CINCHONA ALKALOIDS; 2.4 OTHER POLYMER-IMMOBILIZED CHIRAL BASIC ORGANOCATALYSTS; 2.5 POLYMER-IMMOBILIZED CINCHONA ALKALOID QUATERNARY AMMONIUM SALTS; 2.6 POLYMER-IMMOBILIZED ; MACMILLAN CATALYSTS; 2.7 POLYMER-IMMOBILIZED PYRROLIDINE DERIVATIVES; 2.8 OTHER POLYMER-IMMOBILIZED CHIRAL QUATERNARY AMMONIUM SALTS; 2.9 POLYMER-IMMOBILIZED PROLINE DERIVATIVES; 2.10 POLYMER-IMMOBILIZED PEPTIDES AND POLY(AMINO ACID)S2.11 POLYMER-IMMOBILIZED CHIRAL ACIDIC ORGANOCATALYSTS; 2.12 HELICAL POLYMERS AS CHIRAL ORGANOCATALYSTS; 2.13 CASCADE REACTIONS USING POLYMER-IMMOBILIZED CHIRAL ORGANOCATALYSTS; 2.14 CONCLUSIONS; REFERENCES; 3 ASYMMETRIC SYNTHESIS USING POLYMER-IMMOBILIZED PROLINE DERIVATIVES; 3.1 INTRODUCTION; 3.2 POLYMER-SUPPORTED PROLINE; 3.3 POLYMER-SUPPORTED PROLINAMIDES; 3.4 POLYMER SUPPORTED PROLINE-PEPTIDES; 3.5 POLYMER-SUPPORTED PYRROLIDINES; 3.6 POLYMER-SUPPORTED PROLINOL AND DIARYLPROLINOL DERIVATIVES; 3.7 CONCLUSIONS AND OUTLOOKS; REFERENCES; 4 PEPTIDE-CATALYZED ASYMMETRIC SYNTHESIS4.1 INTRODUCTION; 4.2 POLY(AMINO ACID) CATALYSTS; 4.3 TRI- AND TETRAPEPTIDE CATALYSTS; 4.4 LONGER PEPTIDES WITH A SECONDARY STRUCTURE; 4.5 OTHERS; 4.6 CONCLUSIONS AND OUTLOOKS; REFERENCES; 5 CONTINUOUS FLOW SYSTEM USING POLYMER-SUPPORTED CHIRAL CATALYSTS; 5.1 INTRODUCTION; 5.2 ASYMMETRIC POLYMER-SUPPORTED, METAL-BASED CATALYSTS AND REAGENTS; 5.2.1 Enantioselective Additions to C=O Groups; 5.2.2 Diels-Alder and Related Cycloaddition Reactions; 5.2.3 Enantioslective Cyclopropanation Reactions; 5.2.4 Reduction Reactions; 5.2.5 Oxidation Reactions; 5.3 POLYMER-SUPPORTED ASYMMETRIC ORGANOCATALYSTS5.4 POLYMER-SUPPORTED BIOCATALYSTS; 5.5 CONCLUSIONS; REFERENCES; 6 CHIRAL SYNTHESIS ON POLYMER SUPPORT: A COMBINATORIAL APPROACH; 6.1 INTRODUCTION; 6.2 CHIRAL SYNTHESIS OF COMPLEX POLYFUNCTIONAL MOLECULES ON POLYMER SUPPORT; 6.2.1 Spirocyclic Compound Libraries; 6.2.2 Macrocyclic Compound Libraries; 6.2.3 Heterocyclic Compound Libraries; 6.2.4 Natural-Product-Inspired Compound Libraries; 6.2.5 Libraries Through Combinatorial Decoration of Natural Products; 6.2.6 Divergent Synthesis of Small Molecular Libraries; 6.2.7 Chiral Molecules Through Sequential Use of Polymer-Supported Reagents
• Sommario/riassunto: This book reviews chiral polymer synthesis and its application to asymmetric catalysis. It features the design and use of polymer-immobilized catalysts and methods for their design and synthesis. Chapters cover peptide-catalyzed and enantioselective synthesis, optically-active polymers, and continuous flow processes. It collects recent advances in an important field of polymer and organic chemistry, with leading researchers explaining applications in academic and industry R & D.