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1. |
Record Nr. |
UNINA9910139551803321 |
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Titolo |
Aryl diazonium salts [[electronic resource] ] : new coupling agents in polymer and surface science / / edited by Mohamed Mehdi Chehimi |
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Pubbl/distr/stampa |
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Weinheim, Germany, : Wiley-VCH, 2012 |
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ISBN |
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3-527-65046-6 |
1-280-66568-8 |
9786613642615 |
3-527-65044-X |
3-527-65047-4 |
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Descrizione fisica |
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1 online resource (359 p.) |
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Altri autori (Persone) |
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Disciplina |
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Soggetti |
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Diazo compounds |
Polymers - Surfaces |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Aryl Diazonium Salts: New Coupling Agents in Polymer and Surface Science; Contents; Preface; List of Contributors; 1: Attachment of Organic Layers to Materials Surfaces by Reduction of Diazonium Salts; 1.1: A Brief Survey of the Chemistry and Electrochemistry of Diazonium Salts; 1.2: The Different Methods that Permit Grafting of Diazonium Salts; 1.2.1: Electrochemistry; 1.2.2: Reducing Substrate, Homolytic Dediazonation, Reaction with the Substrate; 1.2.3: Reducing Reagent; 1.2.4: Neutral and Basic Media; 1.2.5: Ultrasonication; 1.2.6: Heating and Microwave; 1.2.7: Mechanical Grafting |
1.2.8: Photochemistry1.3: The Different Substrates, Diazonium Salts, and Solvents that Can Be Used; 1.3.1: Substrates; 1.3.2: Diazonium Salts; 1.3.3: Solvents; 1.4: Evidence for the Presence of a Bond between the Substrate and the Organic Layer; 1.4.1: Stability of the Layer; 1.4.2: Spectroscopic Evidence for a Bond; 1.5: From Monolayers to Multilayers; 1.5.1: Monolayers; 1.5.2: Layers of Medium Thickness; 1.5.2.1 Thick Layers; 1.6: Structure and Formation of Multilayers; 1.6.1: Chemical Structure; 1.6.2: The Spatial Structure of the Layers; 1.6.3: |
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Compactness of the Layers |
1.6.4: Swelling of the Layer1.6.5: Electron Transfer through the Layers; 1.6.6: The Formation Mechanism of Multilayers; 1.7: Conclusion; References; 2: Aryl-Surface Bonding: A Density Functional Theory (DFT)Simulation Approach; 2.1: Introduction; 2.2: Density Functional Theory; 2.3: Bonding between Aryl and Various Substrates; 2.3.1: On Graphite/Graphene; 2.3.1.1 On the Basal Plane; 2.3.1.2 On the Edges of Graphene; 2.3.2: On Carbon Nanotubes; 2.3.3: On Metal Surfaces; 2.4: Summary and Outlook; Acknowledgments; References; 3: Patterned Molecular Layers on Surfaces |
3.1: Methods Based on Scanning Probe Lithography3.1.1: AFM; 3.1.2: SECM; 3.1.3: Spotting; 3.2: Methods Based on Soft Lithography; 3.2.1: Printing; 3.2.2: Molds; 3.2.3: Nanosphere Lithography; 3.3: Methods Based on Lithography; 3.4: Methods Based on Surface-Directed Patterning; 3.4.1: Modification of Si Surfaces; 3.4.2: Modified Electrode Arrays; 3.5: Summary and Conclusions; References; 4: Analytical Methods for the Characterization of Aryl Layers; 4.1: Introduction; 4.2: Scanning Probe Microscopies; 4.3: UV-VIS Spectroscopy: Transmission, Reflection, and Ellipsometry; 4.4: IR Spectroscopy |
4.4.1: Transmission Spectroscopy4.4.2: Reflection Spectroscopy; 4.4.3: Infrared Spectroscopic Ellipsometry (IRSE); 4.4.4: IRSE Surface Characterization; 4.4.5: In Situ IR Spectroscopy: ATR and IRSE; 4.5: Raman Spectroscopy and Surface-Enhanced Raman Scattering (SERS); 4.6: X-ray Photoelectron Spectroscopy (XPS); 4.7: X-ray Standing Waves (XSW); 4.8: Rutherford Backscattering; 4.9: Time of Flight Secondary Ion Mass Spectroscopy; 4.10: Electrochemistry; 4.11: Contact Angle Measurements; 4.12: Conclusion; References; 5: Modification of Nano-objects by Aryl Diazonium Salts; 5.1: Introduction |
5.2: Electrochemical Modification of Nano-objects by Reduction of Diazonium Salts |
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Sommario/riassunto |
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Diazonium compounds are employed as a new class of coupling agents to link polymers, biomacromolecules, and other species (e. g. metallic nanoparticles) to the surface of materials. The resulting high performance materials show improved chemical and physical properties and find widespread applications. The advantage of aryl diazonium salts compared to other surface modifiers lies in their ease of preparation, rapid (electro)reduction, large choice of reactive functional groups, and strong aryl-surface covalent bonding.This unique book summarizes the current knowledge of the surface and |
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2. |
Record Nr. |
UNINA9910782876203321 |
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Autore |
Callaway Barbara J |
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Titolo |
Hildegard Peplau [[electronic resource] ] : psychiatric nurse of the century / / Barbara J. Callaway |
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Pubbl/distr/stampa |
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New York, : Springer Pub. Co., c2002 |
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ISBN |
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Descrizione fisica |
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1 online resource (483 p.) |
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Disciplina |
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610.73/68/092 B |
616.890231 |
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Soggetti |
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Psychiatric nurses - United States |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references (p. 449-452) and index. |
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Nota di contenuto |
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Contents; Foreword; Author's Note; Introduction: A Life of Significance; 1 An American Childhood; 2 Becoming a Nurse; 3 A Nurse Goes to College; 4 World War II: Coming Into Her Own; 5 Transitions; 6 Graduate Studies and Motherhood Too; 7 Teachers College: Beginning a Career; 8 Academic Nightmare: A Career in Crisis; 9 Rutgers: "A Formidable Woman"; 10 Summers on the Road; 11 Rutgers: The Traveling Years; 12 Vision of a Profession; 13 ANA: The Professional Challenge; 14 ANA: The Professional Nightmare; 15 Retirement: "Psychiatric Nurse of the Century"; 16 Conclusion: "Well Done" |
Selected Publications of Hildegard PeplauIndex |
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Sommario/riassunto |
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Hildegard Peplau's 50-year career in nursing left an indelible stamp on the profession of nursing, and on the lives of the mentally ill in this country. She wore many hats -- founder of modern psychiatric nursing, innovative educator, advocate for the mentally ill, proponent of advanced education for nurses, Executive Director and then President of the American Nurses Association, and prolific author. She raised her daughter as a single parent while pursuing an ambitious professional path. Her determined manner often aroused controversy which never deterred her commitment to advancing the nurs |
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3. |
Record Nr. |
UNINA9910154633503321 |
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Autore |
Ismard Paulin |
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Titolo |
Democracy’s Slaves : A Political History of Ancient Greece / / Paulin Ismard |
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Pubbl/distr/stampa |
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Cambridge, MA : , : Harvard University Press, , [2017] |
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©2017 |
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ISBN |
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9780674973800 |
0674973801 |
9780674973787 |
067497378X |
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Descrizione fisica |
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1 online resource (201 pages) |
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Altri autori (Persone) |
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Disciplina |
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Soggetti |
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Slavery - Greece - History |
Public administration - Greece - History |
Slavery - Philosophy |
Greece Social conditions To 146 B.C |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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"Originally published as Démocratie contre les experts: Les esclaves publics en Grèce ancienne, © Editions du Seuil, 2015."--Title page verso. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Frontmatter -- Contents -- Preface -- Introduction -- 1. Genesis -- 2. Servants of the City -- 3. Strange Slaves -- 4. The Democratic Order of Knowledge -- 5. The Mysteries of the Greek State -- Conclusion -- Notes -- Bibliography -- Acknowledgments -- Index |
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Sommario/riassunto |
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The toga-clad statesman of ancient Greece is a familiar figure in the Western political tradition. Less well known is the administrator who ran the state but who was himself a slave. Challenging the modern belief that democracy and bondage are incompatible, Paulin Ismard directs our attention to the cradle of Western democracy, ancient Athens, where the functioning of civic government depended crucially on highly skilled experts who were literally public servants--slaves owned by the city-state rather than by private citizens. Known as demosioi, these public slaves filled a variety of important roles in Athenian society. They were court clerks, archivists, administrators, |
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accountants, and policemen. Many possessed knowledge and skills beyond the attainments of average citizens, and they enjoyed privileges, such as the right to own property, that were denied to private slaves. In effect, demosioi were Western civilization's first civil servants--though they carried out their duties in a condition of bound servitude. Ismard detects a radical split between politics and administrative government at the heart of Athenian democracy. The city-state's managerial caste freed citizens from the day-to-day responsibilities of running the state. By the same token, these public servants were unable to participate in the democratic process because they lacked the rights of full citizenship. By rendering the state's administrators politically invisible, Athens warded off the specter of a government capable of turning against the citizens' will. In a real sense, Ismard shows, Athenian citizens put the success of their democratic experiment in the hands of slaves.-- |
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