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Record Nr. |
UNINA9910139470603321 |
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Titolo |
Chiral amine synthesis [[electronic resource] ] : methods, developments and applications / / edited by Thomas C. Nugent |
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Pubbl/distr/stampa |
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Weinheim, : Wiley-VCH Verlag GmbH & Co., 2010 |
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ISBN |
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1-282-46293-8 |
9786612462931 |
3-527-62954-8 |
3-527-62955-6 |
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Descrizione fisica |
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1 online resource (522 p.) |
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Disciplina |
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Soggetti |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Chiral Amine Synthesis; Foreword; Contents; Preface; List of Contributors; 1 Stereoselective Synthesis of a-Branched Amines by Nucleophilic Addition of Unstabilized Carbanions to Imines; 1.1 Introduction; 1.2 Overview of the Methods for the Preparation of Imines; 1.2.1 N-Aryl and N-Alkyl Imines and Hydrazones; 1.2.2 N-Sulfinyl Imines; 1.2.3 N-Sulfonyl Imines; 1.2.4 N-Phosphinoyl Imines; 1.2.5 N-Acyl and N-Carbamoyl Imines; 1.3 Chiral Auxiliary-Based Approaches; 1.3.1 Imines Derived from Chiral Aldehydes; 1.3.2 Imines Bearing a Chiral Protecting/Activating Group |
1.4 Catalytic Asymmetric Nucleophilic Addition to Achiral Imines1.4.1 Catalytic Asymmetric Addition of sp3 Hybridized Carbanions; 1.4.1.1 Copper-Catalyzed Dialkylzinc Additions; 1.4.1.2 Zinc Alkoxide-Catalyzed Dialkylzinc Additions; 1.4.1.3 Early Transition Metal (Zr, Hf)-Catalyzed Dialkylzinc Additions; 1.4.1.4 Rhodium-Catalyzed Dialkylzinc Addition Reactions; 1.4.2 Catalytic Asymmetric Allylation of Imines; 1.4.3 Catalytic Asymmetric Addition of sp2 Hybridized Carbanions; 1.4.3.1 Catalytic Asymmetric Vinylation; 1.4.3.2 Catalytic Asymmetric Arylation |
1.4.3.2.1 Amino Alcohol-Catalyzed Addition of Organozinc Reagents1. |
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