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Record Nr. |
UNINA9910139027103321 |
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Autore |
Stanley H. E |
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Titolo |
Liquid Polymorphism : Advances in Chemical Physics . Volume 152 |
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Pubbl/distr/stampa |
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ISBN |
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1-118-54037-9 |
1-118-54035-2 |
1-299-44917-4 |
1-118-54036-0 |
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Descrizione fisica |
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1 online resource (654 p.) |
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Collana |
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Advances in Chemical Physics, v. 152 |
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Disciplina |
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Soggetti |
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Chemistry, Physical and theoretical |
Electron |
Spectroscopy |
Polymorphism (Crystallography) |
Liquids |
Chemical & Materials Engineering |
Engineering & Applied Sciences |
Materials Science |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di contenuto |
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Liquid Polymorphism: Advances In Chemical Physics; CONTRIBUTORS TO VOLUME 152; FOREWORD; PREFACE; PREFACE TO THE SERIES; CONTENTS; Electron Spin Resonance Studies of Supercooled Water; I. Introduction; II. Outline of ESR Spectroscopy; A. Spin Probes; B. Rigid-Limit and Motional Narrowing of the Lineshape; C. Accessible Range of the Rotational Dynamics; III. ESR Spectroscopy of Spin Probes: Basic Theoretical Introduction; A. Spin Hamiltonian; B. Lineshape Analysis; 1. No Tumbling: Powder Lineshape; 2. Tumbling: Motional Narrowing of the ESR Lineshape |
IV. ESR Studies of Liquid Water and Aqueous Solutions: A ReviewV. ESR Studies of Confined Water in Polycrystalline Ice; A. Water Confinement in Polycrystalline Ice; B. Location of Paramagnetic Solutes in Water-Ice |
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Mixtures; C. Rotational Dynamics of TEMPOL in Interstitial Water of Polycrystalline Ice; 1. Spin Probe Mobility Above 130K; 2. Dynamical Heterogeneities; 3. Temperature Dependence of the Spin Probe Reorientation; 4. Breakdown of the Debye-Stokes-Einstein Law; 5. Spin Probe Sensing of the Water Static Heterogeneities; 6. Missing Evidence of Additional Impurities in Interstitial Water |
VI. SummaryReferences; Pressure-Driven Liquid-Liquid Transformations and Corresponding Bizarre Viscosity Behavior; I. Introduction; II. Methods; III. Results and Discussions; A. Se; B. AsS; C. As2S3; D. B2O3; IV. Conclusions; References; The Stability Limit and Other Open Questions on Water at Negative Pressure; I. Introduction; II. What is Negative Pressure?; III. The Phase Diagram of Water; IV. Experimental Methods to Generate Tension; A. Acoustic Cavitation; B. Metastable Vapor-Liquid Equilibrium; C. Berthelot Tube; D. Centrifuge Method; V. Limit(s) of Metastability |
A. Comparison Between the Different MethodsB. Origin of the Discrepancy in the Limits of Metastability; C. Remaining Issues with Inclusions; D. Path-Dependent Nucleation; VI. Other Topics in the Study of Liquids Under Tension; A. Equation of State of Water at Negative Pressure; B. Other Properties of Liquid at Negative Pressure; VII. Perspectives; References; Water-Like Anomalies of Core-Softened Fluids: Dependenceon the Trajectories in (PρT ) Space; I. Introduction; II. System and Methods; III. Results and Discussion; A. Diffusion Anomaly; B. Density Anomaly; C. Structural Anomaly |
IV. Rosenfeld ScalingV. Conclusions; References; High-Frequency Dynamics of Liquids Through a Liquid-Liquid Transition: The Case of CS; I. Introduction; II. The Case of Liquid Cesium; III. The Experiment; IV. Results; V. Discussion; VI. Conclusions; References; The Liquid-Liquid Phase Transition, Anomalous Properties, and Glass Behavior of Polymorphic Liquids; I. Introduction; II. Polymorphic Liquids: Phase Diagram, Anomalous Properties, and Glass Behavior; A. Liquid-Liquid Phase Transition; B. Supercritical Region: Anomalous Properties; C. Glass Polymorphism |
III. Computer Simulation Models of Polymorphic Liquids |
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Sommario/riassunto |
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The Advances in Chemical Physics series-the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class de |
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