1.

Record Nr.

UNINA9910137223403321

Titolo

Arene chemistry : reaction mechanisms and methods for aromatic compounds / / edited by Jacques Mortier

Pubbl/distr/stampa

Hoboken, New Jersey : , : Wiley, , 2016

©2016

ISBN

1-118-75498-0

1-118-75495-6

1-118-75488-3

Descrizione fisica

1 online resource (990 p.)

Disciplina

547/.61

Soggetti

Aromatic compounds

Chemistry, Organic

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Includes index.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

TITLE PAGE  ; COPYRIGHT PAGE ; CONTENTS; LIST OF CONTRIBUTORS; PREFACE; Part I Electrophilic Aromatic Substitution ; CHAPTER 1 ELECTROPHILIC AROMATIC SUBSTITUTION: MECHANISM ; 1.1 INTRODUCTION; 1.2 GENERAL ASPECTS; 1.3 ELECTROPHILES; 1.4 ARENE NUCLEOPHILES; 1.5 π-COMPLEX INTERMEDIATES  ; 1.6 σ-COMPLEX OR WHELAND INTERMEDIATES ; 1.7 SUMMARY AND OUTLOOK; ABBREVIATIONS ; REFERENCES ; CHAPTER 2 FRIEDEL-CRAFTS ALKYLATION OF ARENES IN TOTAL SYNTHESIS ; 2.1 INTRODUCTION; 2.2 TOTAL SYNTHESIS INVOLVING INTERMOLECULAR FC ALKYLATIONS; 2.2.1 Synthesis of Coenzyme Q10

2.2.2 Total Synthesis of (±)-Brasiliquinone B 2.2.3 Synthesis of (2212;)-Podophyllotoxin  ; 2.2.4 Synthesis of Puupehenol and Related Compounds; 2.2.5 Synthesis of (2212;)-Talaumidin  ; 2.2.6 Total Synthesis of (±)-Schefferine ; 2.3 TOTAL SYNTHESIS INVOLVING INTRAMOLECULAR FC ALKYLATIONS; 2.3.1 C-C Bond Formation Leading to Homocyclic Rings   ; 2.3.2 C-C Bond Formation Leading to Oxygen-Containing Rings  ; 2.3.3 C-C Bond Formation Leading to Nitrogen-Containing Rings ; 2.4 TOTAL SYNTHESIS THROUGH TANDEM AND CASCADE PROCESSES INVOLVING FC REACTIONS



2.4.1 C-C Bond Formation Leading to Homocyclic Rings 2.4.2 C-C Bond Formation Leading to Oxygen-Containing Rings ; 2.4.3 C-C Bond Formation Leading to Nitrogen-Containing Rings ; 2.5 TOTAL SYNTHESIS INVOLVING ipso-FC REACTIONS ; 2.5.1 Synthesis of (S)-(2212;)-Xylopinine ; 2.5.2 Synthesis of Garcibracteatone; 2.6 SUMMARY AND OUTLOOK; 2.7 ACKNOWLEDGMENT; ABBREVIATIONS ; REFERENCES; CHAPTER 3 CATALYTIC FRIEDEL-CRAFTS ACYLATION REACTIONS ; 3.1 INTRODUCTION AND HISTORICAL BACKGROUND; 3.2 CATALYTIC HOMOGENEOUS ACYLATIONS; 3.2.1 Metal Halides

3.2.2 Perfluoroalkanoic Acids, Perfluorosulfonic Acids, and Their (Metal) Derivatives 3.2.3 Miscellaneous; 3.3 CATALYTIC HETEROGENEOUS ACYLATIONS; 3.3.1 Zeolites; 3.3.2 Clays; 3.3.3 Metal Oxides; 3.3.4 Acid-Treated Metal Oxides ; 3.3.5 Heteropoly Acids (HPAs); 3.3.6 Nafion; 3.3.7 Miscellaneous; 3.4 DIRECT PHENOL ACYLATION; 3.5 SUMMARY AND OUTLOOK; ABBREVIATIONS ; REFERENCES ; CHAPTER 4 THE USE OF QUANTUM CHEMISTRY FOR MECHANISTIC ANALYSES OF SEAr REACTIONS ; 4.1 INTRODUCTION; 4.1.1 Historical Overview of Early Quantum Chemistry Work

4.1.2 Current Mechanistic Understanding Based on Kinetic and Spectroscopic Studies 4.2 THE SEAr MECHANISM: QUANTUM CHEMICAL CHARACTERIZATION IN GAS PHASE AND SOLUTION; 4.2.1 Nitration and Nitrosation; 4.2.2 Halogenation; 4.2.3 Sulfonation; 4.2.4 Friedel-Crafts Alkylations and Acylations; 4.3 PREDICTION OF RELATIVE REACTIVITY AND REGIOSELECTIVITY BASED ON QUANTUM CHEMICAL DESCRIPTORS; 4.4 QUANTUM CHEMICAL REACTIVITY PREDICTION BASED ON MODELING OF TRANSITION STATES AND INTERMEDIATES; 4.4.1 Transition State Modeling; 4.4.2 The Reaction Intermediate or Sigma-Complex Approach

4.5 SUMMARY AND CONCLUSIONS



2.

Record Nr.

UNINA9910793498703321

Titolo

Pocket guide to bacterial infections / / editors, K. Balamurugan and Prithika Udayakumar

Pubbl/distr/stampa

Boca Raton ; ; London ; ; New York : , : CRC Press, Taylor & Francis Group, , [2019]

©2019

ISBN

1-315-16637-2

1-351-67981-3

Descrizione fisica

1 online resource (415 pages)

Collana

Pocket guides to biomedical sciences

Disciplina

616.9/2

Soggetti

Bacterial diseases

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Nota di bibliografia

Includes bibliographical references.

Nota di contenuto

Bacteria causing gastro intestinal tract infections / B. Vinoth, Raja M. Krishna, and B. Agieshkumar -- Gateways of pathogenic bacterial entry into host cells Salmonella / Balakrishnan Senthilkumar, Duraisamy Senbagam, Chidambaram Prahalathan, and Kumarasamy Anbarasu -- Bacteria causing respiratory tract infections / Boopathi Balasubramaniam, Udayakumar Prithika, and Krishnaswamy Balamurugan -- Oral health : a delicate balance between colonization and infection / Ana Moura Teles and José Manuel Cabeda -- Bacterial infections in atherosclerosis : atherosclerosis microbiome / Emil Kozarov and Ann Progulske-Fox -- Neonatal bacterial infection / Koilmani Emmanuvel Rajan and Karen Golda Evangeline -- Bacteria causing orthodontal infections / P.S. Manoharan and Praveen Rajesh -- Bacteria causing orthodontal infections / Charles Solomon, Akino Mercy, and Kalimuthusamy Natarajaseenivasan -- Beneficial lactic acid bacteria / Galina Novik and Victoria Savich -- Bacteria causing in dermatological infections / Thirukannamangai Krishnan Swetha and Shunmugiah Karutha Pandian -- Bacteria causing ophthalmic infections / Arumugam Priya and Shunmugiah Karutha Pandian -- Role of bacteria in urinary tract infections / JebaMercy Gnanasekaran, Kannan Balaji, and Krishnaswarmy Balamurugan -- Role of bacteria in blood infections / Kannan Balaji, Gnanasekaran JebaMercy, and Krishnaswamy



Balamurugan.

Sommario/riassunto

Pocket Guide to Bacterial Infections provides information pertinent to the behaviour of bacterial cells during their interactions with different cell types of multiple host systems. This book will present the role of various bacterial pathogens affecting the host system. The book is to be organized flexibly so that chapters and topics are arranged with continuity from the former chapters. Each chapter has been made as self-contained as possible to promote this flexibility. This book will discuss each of the virulence properties of the bacteria with reference to their interacting hosts in a larger perspective. Kwey selling features: Summarizes the role various bacterial pahtogens affect the host system Reviews recent advances for combating different types of bacterial infections that infect different body parts Designed as an effective teaching and research tool providing up to date information on bacterial infections Defines important terms Written in a readable and direct writing style.