Organic redox systems : synthesis, properties, and applications / / edited by Tohru Nishinaga

• Record Nr.: UNINA9910137222703321
• Pubbl/distr/stampa: Hoboken, New Jersey : , : Wiley, , [2016]; ©2016
• ISBN: 1-118-85885-9; 1-118-85872-7; 1-118-85898-0
• Descrizione fisica: 1 online resource (862 p.)
• Disciplina: 547/.23
• Soggetti: Oxidation-reduction reaction
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: TITLE PAGE; TABLE OF CONTENTS; LIST OF CONTRIBUTORS; PREFACE; 1 INTRODUCTION: BASIC CONCEPTS AND A BRIEF HISTORY OF ORGANIC REDOX SYSTEMS; 1.1 REDOX REACTION OF ORGANIC MOLECULES; 1.2 REDOX POTENTIAL IN NONAQUEOUS SOLVENTS; 1.3 A BRIEF HISTORY OF ORGANIC REDOX COMPOUNDS; REFERENCES; 2 REDOX-MEDIATED REVERSIBLE σ-BOND FORMATION/CLEAVAGE; 2.1 DYNAMIC REDOX ("DYREX") SYSTEMS; 2.2 ADVANCED ELECTROCHROMIC RESPONSE OF "ENDO"-TYPE DYREX SYSTEMS EXHIBITING REDOX SWITCHING OF A σ-BOND; 2.3 ADVANCED ELECTROCHROMIC RESPONSE OF "EXO"-TYPE DYREX SYSTEMS EXHIBITING REDOX SWITCHING OF A σ-BOND; 2.4 PROSPECT: REDOX SYSTEMS WITH MULTIPLE DYREX UNITSREFERENCES; 3 REDOX-CONTROLLED INTRAMOLECULAR MOTIONS TRIGGERED BY π-DIMERIZATION AND PIMERIZATION PROCESSES; 3.1 INTRODUCTION; 3.2 OLIGOTHIOPHENES; 3.3 PHENOTHIAZINE; 3.4 NAPHTHALENE AND PERYLENE BISIMIDES; 3.5 para-PHENYLENEDIAMINE; 3.6 PYRIDINYL RADICALS; 3.7 VIOLOGEN DERIVATIVES; 3.8 VERDAZYL; 3.9 PHENALENYL; 3.10 PORPHYRINS; 3.11 BENZENOID; 3.12 CYCLOPHANE; 3.13 TETRATHIAFULVALENE; 3.14 CONCLUSION; ACKNOWLEDGMENTS; REFERENCES; 4 TETRATHIAFULVALENE: A REDOX UNIT FOR FUNCTIONAL MATERIALS AND A BUILDING BLOCK FOR SUPRAMOLECULAR SELF-ASSEMBLY4.1 ; INTRODUCTION: PAST AND PRESENT OF TTF CHEMISTRY; 4.2 BASIC REDOX PROPERTIES OF TTF AND STACKED TTF; 4.3 TTF AS A FAITHFUL REDOX ACTIVE UNIT IN FUNCTIONAL MATERIALS; 4.4 ELECTROCONDUCTING PROPERTIES OF TTF DERIVATIVES BASED ON SUPRAMOLECULAR SELF-ASSEMBLY; 4.5 SUMMARY AND OUTLOOK; REFERENCES; 5 ROBUST AROMATIC CATION RADICALS AS REDOX TUNABLE OXIDANTS; 5.1 INTRODUCTION; 5.2 DESIGNING MOLECULES FOR THE FORMATION OF STABLE CATION RADICALS (CRs)-A CASE STUDY; 5.3 METHODS OF PREPARATIVE ISOLATION OF AROMATIC CATION RADICALS5.4 QUANTITATIVE OXIDATION OF ELECTRON DONORS USING THE-ORANGE+· SbCl6- AS ONE-ELECTRON OXIDANT; 5.5 READILY AVAILABLE ELECTRON DONORS FOR THE REDOX-TUNABLE AROMATIC OXIDANTS; 5.6 CONCLUSION; REFERENCES; 6 AIR-STABLE REDOX-ACTIVE NEUTRAL RADICALS: TOPOLOGICAL SYMMETRY CONTROL OF ELECTRONIC-SPIN, MULTICENTERED CHEMICAL BONDING, AND ORGANIC BATTERY APPLICATION; 6.1 INTRODUCTION; 6.2 OPEN-SHELL GRAPHENE FRAGMENT: DESIGN AND SYNTHESIS OF AIR-STABLE CARBON-CENTERED NEUTRAL RADICALS BASED ON FUSED-POLYCYCLIC Π-SYSTEM; 7.5 THE LENGTH OF THE BRIDGE