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Record Nr. |
UNINA9910132192503321 |
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Titolo |
Developments in electrochemistry : science inspired by Martin Fleischmann / / editors, Derek Pletcher, Zhong-Qun Tian, David E. Williams |
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Pubbl/distr/stampa |
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Chichester, England : , : Wiley, , 2014 |
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©2014 |
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ISBN |
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1-118-69440-6 |
1-118-69434-1 |
1-118-69438-4 |
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Descrizione fisica |
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1 online resource (393 p.) |
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Disciplina |
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Soggetti |
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Electrochemistry |
Spectrum analysis |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Nota di bibliografia |
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Includes bibliographical references at the end of each chapters and index. |
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Nota di contenuto |
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Developments in Electrochemistry; Contents; List of Contributors; 1 Martin Fleischmann - The Scientist and the Person; The Publications of Martin Fleischmann; 2 A Critical Review of the Methods Available for Quantitative Evaluation of Electrode Kinetics at Stationary Macrodisk Electrodes; 2.1 DC Cyclic Voltammetry; 2.1.1 Principles; 2.1.2 Processing DC Cyclic Voltammetric Data; 2.1.3 Semiintegration; 2.2 AC Voltammetry; 2.2.1 Advanced Methods of Theory-Experiment Comparison; 2.3 Experimental Studies; 2.3.1 Reduction of [Ru(NH3)6]3+ in an Aqueous Medium |
4.2 Electrochemical Nucleation with Diffusion-Controlled Growth4.3 Mathematical Modeling of Nucleation and Growth Processes; 4.4 The Nature of Active Sites; 4.5 Induction Times and the Onset of Electrochemical Phase Formation Processes; 4.6 Conclusion; References; 5 Organic Electrosynthesis; 5.1 Indirect Electrolysis; 5.2 Intermediates for Families of Reactions; 5.3 Selective Fluorination; 5.4 Two-Phase Electrolysis; 5.5 Electrode Materials; 5.6 Towards Pharmaceutical Products; 5.7 Future Prospects; References; 6 Electrochemical Engineering and Cell Design |
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6.1 Principles of Electrochemical Reactor Design6.1.1 Cell Potential; 6.1.2 The Rate of Chemical Change; 6.2 Decisions During the Process of Cell Design; 6.2.1 Strategic Decisions; 6.2.2 Divided and Undivided Cells; 6.2.3 Monopolar and Bipolar Electrical Connections to Electrodes; 6.2.4 Scaling the Cell Current; 6.2.5 Porous 3D Electrode Structures; 6.2.6 Interelectrode Gap; 6.3 The Influence of Electrochemical Engineering on the Chlor-Alkali Industry; 6.4 Parallel Plate Cells; 6.5 Redox Flow Batteries; 6.6 Rotating Cylinder Electrode Cells; 6.7 Conclusions; References |
7 Electrochemical Surface-Enhanced Raman Spectroscopy (EC-SERS): Early History, Principles, Methods, and Experiments7.1 Early History of Electrochemical Surface-Enhanced Raman Spectroscopy; 7.2 Principles and Methods of SERS; 7.2.1 Electromagnetic Enhancement of SERS; 7.2.2 Key Factors Influencing SERS; 7.2.3 "Borrowing SERS Activity" Methods; 7.2.4 Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy; 7.3 Features of EC-SERS; 7.3.1 Electrochemical Double Layer of EC-SERS Systems; 7.3.2 Electrolyte Solutions and Solvent Dependency; 7.4 EC-SERS Experiments |
7.4.1 Measurement Procedures for EC-SERS |
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Sommario/riassunto |
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Martin Fleischmann was truly one of the 'fathers' of modern electrochemistry having made major contributions to diverse topics within electrochemical science and technology. These include the theory and practice of voltammetry and in situ spectroscopic techniques, instrumentation, electrochemical phase formation, corrosion, electrochemical engineering, electrosynthesis and cold fusion. While intended to honour the memory of Martin Fleischmann, Developments in Electrochemistry is neither a biography nor a history of his contributions. Rather, the book is a series of crit |
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