1.

Record Nr.

UNINA9910132190803321

Autore

Ghosh Arun K.

Titolo

Structure-based design of drugs and other bioactive molecules : tools and strategies / / Arun K. Ghosh and Sandra Gemma

Pubbl/distr/stampa

Weinheim, Germany : , : Wiley-VCH, , 2014

©2014

ISBN

3-527-66523-4

3-527-66521-8

3-527-66524-2

Descrizione fisica

1 online resource (476 p.)

Disciplina

615.190285

Soggetti

Drug development - Data processing

Bioactive compounds - Analysis

Biopolymers

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references at the end of each chapters and index.

Nota di contenuto

Structure-based Design of Drugs and Other Bioactive Molecules: Tools and Strategies; Contents; Preface; 1 From Traditional Medicine to Modern Drugs: Historical Perspective of Structure-Based Drug Design; 1.1 Introduction; 1.2 Drug Discovery During 1928-1980; 1.3 The Beginning of Structure-Based Drug Design; 1.4 Conclusions; References; Part One: Concepts, Tools, Ligands, and Scaffolds for Structure-Based Design of Inhibitors; 2 Design of Inhibitors of Aspartic Acid Proteases; 2.1 Introduction; 2.2 Design of Peptidomimetic Inhibitors of Aspartic Acid Proteases

2.3 Design of Statine-Based Inhibitors2.4 Design of Hydroxyethylene Isostere-Based Inhibitors; 2.5 Design of Inhibitors with Hydroxyethylamine Isosteres; 2.5.1 Synthesis of Optically Active α-Aminoalkyl Epoxide; 2.6 Design of (Hydroxyethyl)urea-Based Inhibitors; 2.7 (Hydroxyethyl)sulfonamide-Based Inhibitors; 2.8 Design of Heterocyclic/Nonpeptidomimetic Aspartic Acid Protease Inhibitors; 2.8.1 Hydroxycoumarin- and Hydroxypyrone-Based Inhibitors; 2.8.2 Design of Substituted Piperidine-Based Inhibitors; 2.8.3 Design of



Diaminopyrimidine-Based Inhibitors

2.8.4 Design of Acyl Guanidine-Based Inhibitors2.8.5 Design of Aminopyridine-Based Inhibitors; 2.8.6 Design of Aminoimidazole- and Aminohydantoin-Based Inhibitors; 2.9 Conclusions; References; 3 Design of Serine Protease Inhibitors; 3.1 Introduction; 3.2 Catalytic Mechanism of Serine Protease; 3.3 Types of Serine Protease Inhibitors; 3.4 Halomethyl Ketone-Based Inhibitors; 3.5 Diphenyl Phosphonate-Based Inhibitors; 3.6 Trifluoromethyl Ketone Based Inhibitors; 3.6.1 Synthesis of Trifluoromethyl Ketones; 3.7 Peptidyl Boronic Acid-Based Inhibitors

3.7.1 Synthesis of α-Aminoalkyl Boronic Acid Derivatives3.8 Peptidyl α-Ketoamide- and α-Ketoheterocycle-Based Inhibitors; 3.8.1 Synthesis of α-Ketoamide and α-Ketoheterocyclic Templates; 3.9 Design of Serine Protease Inhibitors Based Upon Heterocycles; 3.9.1 Isocoumarin-Derived Irreversible Inhibitors; 3.9.2 β-Lactam-Derived Irreversible Inhibitors; 3.10 Reversible/Noncovalent Inhibitors; 3.11 Conclusions; References; 4 Design of Proteasome Inhibitors; 4.1 Introduction; 4.2 Catalytic Mechanism of 20S Proteasome; 4.3 Proteasome Inhibitors; 4.3.1 Development of Boronate Proteasome Inhibitors

4.3.2 Development of β-Lactone Natural Product-Based Proteasome Inhibitors4.3.3 Development of Epoxy Ketone-Derived Inhibitors; 4.3.4 Noncovalent Proteasome Inhibitors; 4.4 Synthesis of β-Lactone Scaffold; 4.5 Synthesis of Epoxy Ketone Scaffold; 4.6 Conclusions; References; 5 Design of Cysteine Protease Inhibitors; 5.1 Introduction; 5.2 Development of Cysteine Protease Inhibitors with Michael Acceptors; 5.3 Design of Noncovalent Cysteine Protease Inhibitors; 5.4 Conclusions; References; 6 Design of Metalloprotease Inhibitors; 6.1 Introduction; 6.2 Design of Matrix Metalloprotease Inhibitors

6.3 Design of Inhibitors of Tumor Necrosis Factor-α-Converting Enzymes

Sommario/riassunto

In contrast to previous texts focusing on either computational, structural or synthetic methods, this one-of-a-kind guide integrates all three skill sets for a complete picture of contemporary structure-based design.As a result, this practical book demonstrates how to develop a high-affinity ligand with drug-like properties for any given drug target for which a high-resolution structure exists. The authors, both of whom have successfully designed drug-like molecules that were later developed into marketed drugs, use numerous examples of recently developed drugs to present best practice in



2.

Record Nr.

UNINA9910778627103321

Titolo

The role of small satellites in NASA and NOAA earth observation programs [[electronic resource] /] / Committee on Earth Studies, Space Studies Board, Commission on Physical Sciences, Mathematics, and Applications, National Research Council

Pubbl/distr/stampa

Washington, D.C., : National Academy Press, c2000

ISBN

0-309-18370-7

1-280-18552-X

9786610185528

0-309-59409-X

0-585-25489-3

Descrizione fisica

1 online resource (104 p.)

Disciplina

550/.28

Soggetti

Microspacecraft - United States

Artificial satellites in earth sciences - United States

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

"Support for this project was provided by Contract NASW 96013 between the National Academy of Sciences and the National Aeronautics and Space Administration"--T.p. verso.

Nota di bibliografia

Includes bibliographical references.

Nota di contenuto

""THE ROLE OF SMALL SATELLITES IN NASA AND NOAA EARTH OBSERVATION PROGRAMS""; ""Copyright""; ""Foreword""; ""Acknowledgment of Reviewers""; ""Contents""; ""Executive Summary""; ""SMALL SATELLITES VERSUS SMALL MISSIONS""; ""MEETING CORE OBSERVATIONAL NEEDS""; ""CAPABILITY OF SMALL SATELLITES TO PERFORM EARTH OBSERVATION MISSIONS""; ""FLEXIBILITY AND NEW OPPORTUNITIES PROVIDED BY SMALL SATELLITES""; ""AVAILABILITY OF RELIABLE LAUNCH VEHICLES""; ""COST OF SMALL SATELLITE MISSIONS""; ""SENSOR DEVELOPMENT""; ""MISSION ARCHITECTURE""; ""MANAGEMENT OF SMALL SATELLITE PROGRAMS""; ""MISSION PLANNING""

""CONCLUSION""""1 Introduction ""; ""REFERENCES""; ""2 Core Observational Needs ""; ""REQUIRED MEASUREMENTS""; ""Measurements in Support of Climate and Global Change Research""; ""Measurements in Support of Operational Applications""; ""CHARACTERIZATION,



CALIBRATION, AND VALIDATION""; ""Prelaunch Sensor Characterization""; ""Calibration""; ""Validation""; ""DATA CONTINUITY""; ""Operational Data Continuity""; ""Data Continuity in Research""; ""SIMULTANEITY""; ""SAMPLING ERRORS""; ""SUMMARY""; ""REFERENCES""; ""3 Payload Sensor Characteristics ""

""PAYLOAD DESIGN AND ACCOMMODATION REQUIREMENTS""""CURRENTLY PLANNED SENSORS""; ""SENSOR COSTS""; ""FUTURE SENSOR DESIGNS: IMPLICATIONS OF ADVANCED TECHNOLOGIES""; ""Size and Design Constraints""; ""Fundamental Limits on Size""; ""Technological Limits on Size""; ""Measurement Strategies and Mission Architectures""; ""SUMMARY""; ""4 Small Satellite Buses ""; ""CAPABILITIES OF SMALL SATELLITE BUSES""; ""SPACECRAFT BUS COSTS""; ""UTILITY OF ""COMMERCIAL"" SPACECRAFT""; ""SPACECRAFT CAPABILITY AS A PAYLOAD DESIGN PARAMETER""; ""PRINCIPAL INVESTIGATOR-LED PROJECTS""; ""FUTURE TRENDS""; ""SUMMARY""

""REFERENCES""""5 Small Launch Vehicles""; ""SMALL LAUNCH VEHICLES FOR EOS AND NPOESS""; ""SUMMARY""; ""6 Small Satellites and Mission Architectures ""; ""OPTIONS FOR DISTRIBUTING SENSORS""; ""Single-Sensor Platforms""; ""Multisensor Platforms""; ""Clusters""; ""Constellations""; ""COST-EFFECTIVENESS OF SMALL SATELLITE ARCHITECTURES""; ""Maintenance""; ""NPOESS""; ""EOS""; ""SUMMARY""; ""REFERENCES""; ""7 Opportunities and Challenges in Managing Small Satellite Systems ""; ""PROGRAMMATIC APPROACHES TO TECHNICAL ISSUES""; ""RISKS""; ""Programmatic Risks""; ""Management of Programmatic Risks""

""Hidden Programmatic Costs""""Scientific Risks""; ""Management of Scientific Risks""; ""Hidden Scientific Costs""; ""SUMMARY""; ""REFERENCES""; ""8 Findings and Recommendations ""; ""MISSION COSTS""; ""MEETING MISSION GOALS: OPPORTUNITIES WITH SMALL SATELLITES""; ""OPERATIONAL AND RESEARCH EARTH OBSERVATIONS""; ""PAYLOADS""; ""SATELLITE BUSES""; ""LAUNCH VEHICLES""; ""MISSION ARCHITECTURES""; ""SYSTEM MANAGEMENT""; ""SUMMARY""; ""Appendixes""; ""A Statement of Task ""; ""ANALYSIS OF SMALL SATELLITE CAPABILITIES IN LIGHT OF SCIENCE REQUIREMENTS FOR CORE OBSERVATIONAL NEE...""

""B Effects of Technology on Sensor Size and Design ""