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Record Nr. |
UNINA9910131380603321 |
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Autore |
Marcus Y. |
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Titolo |
Ions in solution and their solvation / / Yizhak Marcus |
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Pubbl/distr/stampa |
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Hoboken, New Jersey : , : Wiley, , 2015 |
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©2015 |
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ISBN |
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1-118-89227-5 |
1-118-89233-X |
1-118-89230-5 |
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Edizione |
[1st ed.] |
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Descrizione fisica |
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1 online resource (311 p.) |
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Disciplina |
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Soggetti |
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Ionic solutions |
Ions |
Solution (Chemistry) |
Solvation |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references at the end of each chapters and indexes. |
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Nota di contenuto |
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Title Page; Copyright Page; Contents; Preface; Chapter 1 Introduction; 1.1 THE SIGNIFICANCE AND PHENOMENOLOGY OF IONS IN SOLUTION; 1.2 LIST OF SYMBOLS AND ABBREVIATIONS; PRINCIPAL LATIN CHARACTERS; PRINCIPAL GREEK CHARACTERS; PRINCIPAL SUBSCRIPTS; PRINCIPAL SUPERSCRIPTS; Chapter 2 Ions and Their Properties; 2.1 IONS AS ISOLATED PARTICLES; 2.1.1 Bare Ions; 2.1.2 Ions in Clusters; 2.2 SIZES OF IONS; 2.3 IONS IN SOLUTION; 2.3.1 Thermodynamics of Ions in Aqueous Solutions; 2.3.1.1 Heat Capacities of Aqueous Ions; 2.3.1.2 Entropies of Aqueous Ions; 2.3.1.3 Enthalpies of Formation of Aqueous Ions |
2.3.1.4 Gibbs Energies of Formation of Aqueous Ions 2.3.1.5 Ionic Molar Volumes in Aqueous Solutions; 2.3.2 Other Properties of Aqueous Ions; 2.3.2.1 Ionic Conductivities in Aqueous Solutions; 2.3.2.2 Ionic Self-Diffusion in Aqueous Solutions; 2.3.2.3 Ionic Effects on the Viscosity; 2.3.2.4 Ionic Effects on the Relaxation of NMR Signals; 2.3.2.5 Ionic Dielectric Decrements; 2.3.2.6 Ionic Effects on the Surface Tension; REFERENCES; Chapter 3 Solvents for Ions; 3.1 SOLVENT |
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PROPERTIES THAT SUIT ION DISSOLUTION; 3.2 PHYSICAL PROPERTIES OF SOLVENTS; 3.2.1 Volumetric Properties |
3.2.2 Thermodynamic Properties 3.2.3 Electrical, Optical, and Magnetic Properties; 3.2.4 Transport Properties; 3.3 CHEMICAL PROPERTIES OF SOLVENTS; 3.3.1 Structuredness; 3.3.2 Solvent Properties Related to Their Ion Solvating Ability; 3.3.2.1 Polarity; 3.3.2.2 Electron Pair Donicity and Ability to Accept a Hydrogen Bond; 3.3.2.3 Hydrogen Bond Donicity and Electron Pair Acceptance; 3.3.2.4 Softness; 3.3.3 Solvents as Acids and Bases; 3.3.4 Miscibility with and Solubility in Water; 3.3.5 Spectroscopic and Electrochemical Windows; 3.4 PROPERTIES OF BINARY AQUEOUS COSOLVENT MIXTURES |
3.4.1 Physical Properties of Binary Aqueous Mixtures with Cosolvents 3.4.1.1 Thermodynamic Properties of the Mixtures; 3.4.1.2 Some Electrical, Optical, and Transport Properties of the Mixtures; 3.4.2 Chemical Properties of Binary Aqueous Mixtures with Cosolvents; 3.4.2.1 Structuredness; 3.4.2.2 Properties Related to the Ion Solvating Ability; REFERENCES; Chapter 4 Ion Solvation in Neat Solvents; 4.1 THE SOLVATION PROCESS; 4.2 THERMODYNAMICS OF ION HYDRATION; 4.2.1 Gibbs Energies of Ion Hydration; 4.2.1.1 Accommodation of the Ion in a Cavity; 4.2.1.2 Electrostatic Interactions |
4.2.2 Entropies of Ion Hydration 4.2.3 Enthalpies of Ion Hydration; 4.3 TRANSFER THERMODYNAMICS INTO NONAQUEOUS SOLVENTS; 4.3.1 Selection of an Extra-Thermodynamic Assumption; 4.3.2 Thermodynamics of Transfer of Ions into Nonaqueous Solvents; 4.3.2.1 Gibbs Energies of Transfer; 4.3.2.2 Enthalpies of Transfer; 4.3.2.3 Entropies of Transfer; 4.3.2.4 Ionic Heat Capacities in Nonaqueous Solvents; 4.3.2.5 Ionic Volumes in Nonaqueous Solvents; 4.4 THE STRUCTURE OF SOLVATED IONS; 4.4.1 Hydration Numbers from Diffraction Studies; 4.4.2 Hydration Numbers from Computer Simulations |
4.4.3 Hydration Numbers from Bulk Properties |
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Sommario/riassunto |
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The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions |
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